| 热解-气相色谱法研究卤素在聚烯烃中的阻燃机理 |
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| 引用本文： | 薛恩钰,马志领,丁天惠.热解-气相色谱法研究卤素在聚烯烃中的阻燃机理[J].河北大学学报(自然科学版),1988(3). |
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| 作者姓名： | 薛恩钰 马志领 丁天惠 |
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| 作者单位： | 河北大学化学系
(薛恩钰，马志领)，河北大学化学系(丁天惠) |
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| 摘 要： | 本文研究了含溴阻燃剂阻燃的聚烯烃。氧指数测定表明,聚烯烃的结构对溴阻燃剂的阻燃效果有显著影响。对比阻燃聚烯烃和非阻燃聚烯烃的裂解产物,发现阻燃聚烯烃的裂解产物中,烷烃的浓度增大,烯烃的浓度降低。据此讨论了卤素的氢转移阻燃作用机理。
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| 关 键 词： | 阻燃 色谱 卤素 聚烯烃 |
Pyrolysis Gas Chromatograph - Study the Fireproofing Machanism of Halogen in polyolefin |
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| Xu Enyu Ma Zhiling Ding Tianhui.Pyrolysis Gas Chromatograph - Study the Fireproofing Machanism of Halogen in polyolefin[J].Journal of Hebei University (Natural Science Edition),1988(3). |
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| Authors: | Xu Enyu Ma Zhiling Ding Tianhui |
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| Affiliation: | Department of Chemistry |
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| Abstract: | polyolefin fireproofed by bromine f lameretardant s have been invest igatcd. OI exhibited that structure of polyolefin affect the effect of bromine flameretardants . The pyrolysis products of fireproofing polyolefin compared with that of nonfireproo f in g polyolefin, alkane are increased, olefin are decreased. Then, the Hydrogen removed fireproofing machanism of halogen are discussed. |
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| Keywords: | Fireproofing chromatograph Halogen polyolefin |
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