| 紫外光辐照反-1,4-聚异戊二烯/碳纳米管复合材料 |
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| 引用本文： | 官文超,李学锋,刘勇霞.紫外光辐照反-1,4-聚异戊二烯/碳纳米管复合材料[J].合成橡胶工业,2003,26(6):365-367. |
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| 作者姓名： | 官文超 李学锋 刘勇霞 |
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| 作者单位： | 1. 华中科技大学,化学系,湖北,武汉,430074
2. 湖北工学院,化工系,湖北,武汉,430068 |
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| 基金项目： | 国家自然科学基金资助项目 ( 2 0 0 740 12 ) |
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| 摘 要： | 在室温和氮气环境下 ,用反 - 1,4 -聚异戊二烯 (TPI)与碳纳米管 (CNT)经紫外光辐照制备了TPI/CNT复合材料。实验表明 ,TPI与CNT的复合材料或二者直接共混物的电阻率 (ρv)均随CNT质量分数的增加而下降 ;前者的导电性优于后者。CNT质量分数为 5 %时 ,TPI/CNT复合材料的 ρv 与TPI相比 ,下降了 7个数量级 ,为 6 .0 7× 10 8Ω·cm。在紫外光辐照下 ,CNT可在TPI基质中均匀分布 ,形成导电网络
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| 关 键 词： | 反-1，4-聚异戊二烯 碳纳米管 紫外光辐照 复合材料 导电性 |
| 文章编号： | 1000-1255(2003)06-0365-03 |
Ultraviolet irradiated trans-polyisoprene/carbon nanotubes composites |
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| Guan Wenchao ,Li Xuefeng ,Liu Yongxia.Ultraviolet irradiated trans-polyisoprene/carbon nanotubes composites[J].China Synthetic Rubber Industry,2003,26(6):365-367. |
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| Authors: | Guan Wenchao Li Xuefeng Liu Yongxia |
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| Affiliation: | Guan Wenchao 1,Li Xuefeng 2,Liu Yongxia 2 |
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| Abstract: | Carbon nanotubes (CNT) and a solution of trans-polyisoprene(TPI) were irradiated using ultraviolet (UV) at room temperature and under the protection of N 2.The results of FTIR and FS showed that CNT was chemically linked to the TPI. The resistivity of TPI/CNT composites gradually decreased with increasing of mass fraction of CNT.The electrical conductivity of UV irradiated TPI/CNT composites were greatly better than that of directly blended TPI/CNT. CNT exhibited good dispersion and easy formation of electrical conductivity networks in the UV irradiated TPI matrix as observed by SEM. |
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| Keywords: | trans-polyisoprene carbon nanotube ultraviolet irradiation composite electrical conductivity |
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