| 二氧化硅负载聚－γ－氨丙基硅氧烷－钌－钴双金属络合物催化烯烃醛化反应的研究 |
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| 引用本文： | 唐黎明,关士友,黄美玉,江英彦.二氧化硅负载聚－γ－氨丙基硅氧烷－钌－钴双金属络合物催化烯烃醛化反应的研究[J].石油化工,1995(7). |
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| 作者姓名： | 唐黎明 关士友 黄美玉 江英彦 |
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| 作者单位： | 中国科学院化学研究所 |
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| 摘 要： | 合成了高活性烯烃醛化催化剂，二氧化硅负载聚．－γ－氨丙基硅氧烷－钌－钴双金属络合物（ＳｉＯ＿２－Ｓｉ－ＮＨ＿２－Ｒｕ－Ｃｏ），ＸＰＳ和ＩＲ分析表明，络合物中氮原子与金属间形成了配应键．研究对苯乙烯醛化反应的最佳条件为：Ｒｕ／Ｃｏ摩尔比２／１，温度１３０－１４０℃，ＣＯ／Ｈ＿２比为１／１－１／２。该催化剂稳定性高，可重复使用。
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| 关 键 词： | 二氧化硅负载聚－γ－氨丙基硅氧烷，钌－钴双金属络合物，烯烃，催化醛化 |
Hydroformylation of Olefins Catalyzed by a Silica-supported Poly-γ- aminopropylsiloxane-Ruthenium-Cobalt Bimetallic Complex |
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| Tang Liming,Guan Shiyou,Huang Meiyu and Jiang Yingyan.Hydroformylation of Olefins Catalyzed by a Silica-supported Poly-γ- aminopropylsiloxane-Ruthenium-Cobalt Bimetallic Complex[J].Petrochemical Technology,1995(7). |
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| Authors: | Tang Liming Guan Shiyou Huang Meiyu and Jiang Yingyan |
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| Abstract: | An effective hydroformylation catalyst,silica-supported poly-γ-aminopropylsiloxane-rutheni-um-cobalt bimeta11ic complex(abbreviated as SiO_2-Si-NH_2-Ru-Co)has been prepared. XPS and IRanalysis showed that coordination bonds were formed between nitrogen and metals in the com-plex. The optimal reaction conditions for hydroformylation of stvrene were found to be:Ru/Comolar ratio of 2/l,temperature of l30-l40℃and CO/H_2 ratio of1/1-1/2.The catalyst was sta-ble during the reaction and could be used repeatedly. |
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| Keywords: | silica-supported poly-γ-aminopropylsiloxane ruthenium-cobalt bimetallic complex olefins catalytic hydroformylation |
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