| 含膦配体的钴镍络合物的合成及催化性能 |
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| 引用本文： | 赵维君,方延铨,张书笈,黄唯平,张新杰,田英芬,杨秀檀.含膦配体的钴镍络合物的合成及催化性能[J].天然气化工,1994(1). |
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| 作者姓名： | 赵维君 方延铨 张书笈 黄唯平 张新杰 田英芬 杨秀檀 |
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| 作者单位： | 南开大学化学系 |
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| 摘 要： | 合成了含二苯基吡啶基膦、三苯基膦、三对甲基苯基膦、双（二苯基膦基）甲烷、双（二苯基膦基）乙烷等配体的钴和镍的络合物。考察了这些络合物对乙醇羰基化制丙酸乙酯的催化性能，比较了这些不同配体对催化反应的影响。
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| 关 键 词： | 钴镍络合物，乙醇羰基化，催化性能 |
Synthesis and catalytic properties of cobolt and nickel complexes containing phosphine ligands |
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| Zhao Weijun,Fang Yanquan,Zhang Shuji,Huang Weiping,Zhang Xinjie,Tian Yingfe, YangXiutan.Synthesis and catalytic properties of cobolt and nickel complexes containing phosphine ligands[J].Natural Gas Chemical Industry,1994(1). |
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| Authors: | Zhao Weijun Fang Yanquan Zhang Shuji Huang Weiping Zhang Xinjie Tian Yingfe YangXiutan |
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| Abstract: | Some cobolt and nickel complexes containing phosphine ligands have beed synthesized by the authors. The phosphine ligands include 2-(diphenylphosphino) pyridine,triphenylphosphine, tri-p-methylphenylphosphine, bis (diphenylphosphino-) methane and bis (diphenylphosphino-) ethane. The catalytic properties of these complexes for carbonylation of ethyl alcohol to ethyl propionate have been investigated and the effects of them on the catalytic reaction have been compared. |
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| Keywords: | cobolt-nickel complex carbonylation of ethanol catalytic properties |
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