| 增塑剂邻苯二甲酸二丁酯的绿色合成 |
| |
| 引用本文： | 柴凤兰,徐海云,杨诗佳.增塑剂邻苯二甲酸二丁酯的绿色合成[J].陕西化工,2014(3):465-467. |
| |
| 作者姓名： | 柴凤兰 徐海云 杨诗佳 |
| |
| 作者单位： | [1]河南化工职业学院,河南郑州450042 [2]河南省有色金属地质矿产局,河南郑州450016 |
| |
| 基金项目： | 河南省高等学校自然科学研究基金资助项目（2011A150009） |
| |
| 摘 要： | 用一水合硫酸氢钠催化邻苯二甲酸酐和正丁醇酯化反应,合成邻苯二甲酸二丁酯（DBP）,最佳反应条件为：正丁醇与苯酐的摩尔比为2.5∶1,催化剂与苯酐摩尔比为1∶500,反应温度195℃,反应2h,酯化率98.5％,DBP的产率96％,纯度＞99.8％;苯酐消耗定额＜0.6,正丁醇消耗定额＜0.7.催化剂安全、经济,不污染环境,符合绿色合成化学原则.
|
| 关 键 词： | 增塑剂 邻苯二甲酸二丁酯 邻苯二甲酸酐 绿色合成 |
Green synthesis of plasticizer dibutyl phthalate |
| |
| CHAI Feng-lanHenan Vocational College of Chemical Technology,Zhengzhou,China XU Hai-yunHenan Vocational College of Chemical Technology,Zhengzhou,China YANG Shi-jia.Green synthesis of plasticizer dibutyl phthalate[J].Applied Chemical Industry,2014(3):465-467. |
| |
| Authors: | CHAI Feng-lanHenan Vocational College of Chemical Technology Zhengzhou China XU Hai-yunHenan Vocational College of Chemical Technology Zhengzhou China YANG Shi-jia |
| |
| Affiliation: | CHAI Feng-lan(Henan Vocational College of Chemical Technology ,Zhengzhou 450042,China) XU Hai-yun(Henan Vocational College of Chemical Technology ,Zhengzhou 450042,China) YANG Shi-jia(Henan Provincial Non-Ferrous Metals Geological and Mineral Resources Bureau,Zhengzhou 450016, China) |
| |
| Abstract: | The dibutyl phthalate was synthesized with NaHSO4 · H2O as catalyst by esterification of phthalic anhydride and n-butanol.The optimal reaction parameters for the process were obtained as follows：the molar ratio of n-butanol to phthalic anhydride was 2.5 ∶ 1,and that of the catalyst to phthalic anhydride was 1∶500,the reaction temperature was 195 ℃ and the reaction time was 2h,esterification rate was up to 98.5％.The yield for dibutyl phthalate was 96％,the fincness for dibutyl phthalate was ＞ 99.8％.The consumption quota of phthalic anhydride was ＜ 0.6 and that of n-butanol was ＜ 0.7.The catalyst was safe,economic and no environmental pollution,which agrees with the principles of green synthesis chemistry. |
| |
| Keywords: | plasticizer dibutyl phthalate phthalic anhydride green synthesis |
| 本文献已被 维普 等数据库收录！ |
|
