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A Series Piezoelectric Quartz Crystal Response Kinetics for T.ferrooxidans Growth in the Presence of Cu(Ⅱ)
作者姓名:CHAI Li yuan    WEI Wan zhi  YAO Shou zhuo
作者单位:1. Department of Metallurgical Science and Engineering,Central South University of Technology,Changsha 410083,China; 2. College of Chemistry and Chemical Engineering,Hunan University,Changsha
基金项目:TheNationalPostdoctoralFundinChina(No .4421)
摘    要:Inbiohydrometallurgy ,T .ferrooxidansisoneofthemostimportantmicroorganisms1]fortheextractionofbasemetalsincludingcopper2~ 4 ],nickel5,6 ],zinc7],lead8]etc ,andthepretreatmentofarsenicrefractorygoldores9~ 12 ].ThestudiesonthegrowthofT .ferrooxidanshavebeenconducted…

收稿时间:13 October 1999

A series piezoelectric quartz crystal response kinetics for T. ferrooxidans growth in the presence of Cu(II)
CHAI Li yuan ,,WEI Wan zhi ,YAO Shou zhuo .A series piezoelectric quartz crystal response kinetics for T. ferrooxidans growth in the presence of Cu(II)[J].Journal of Central South University of Technology,2000,7(1):15-19.
Authors:Chai Li-yuan  Wei Wan-zhi and Yao Shou-zhuo
Affiliation:(1) Department of Metallurgical Science and Engineering, Central South University of Technology, 410083 Changsha, China;(2) College of Chemistry and Chemical Engineering, Hunan University, 410082 Changsha, China
Abstract:The kinetics on the growth of T. ferroxidans in the presence of Cu(II) was studied using of series piezoelectric quartz crystal (SPQC). Arsenic ion inhibits the growth of T. ferrooxidans, which is consistent with the previous results by other measuring methods. This further demonstrates that the SPQC can monitor the chemical activity of T. ferrooxidans growth. Cupric ion accelerates the growth of T. ferrooxidans. The mechanism was discussed, i. e., copper promotes the protein enzyme of T. ferrooxidans, rusticyanin, to form over the range of cupric ion concentration studied. The reaction order of cupric ion in accelerating the bacterial growth is 0.067. The growth of T. ferrooxidans is dependent on temperature, the apparent reaction activation energy decreases from 25.56 kJ/mol to 18.32 kJ/mol because of the addition of 10 mg/L Cu(II) to the bacterial growth solution of pH 2.0 at initial inoculum of 10%. Foundation item: The National Postdoctoral Fund in China(No. 4421) Biography of the first author: CHAI Li-yuan, professor, born in 1966, obtained Doctor degree of Engineering in 1997. Interested research fields: Hydrometallurgy or biohydrometallurgy, especially of gold; preparation of novel functional powders; recycling of nonferrous metals and environmental protection.
Keywords:series piezoelectric quartz crystal  T  ferrooxidans  growth kinetics  sigmoid curve  cupric ion
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