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Production of defluorinated dicalcium phosphate from phosphate rock concentrate
Authors:AMB Freitas  M Giulietti
Affiliation:1. Chemical Engineering Department, Federal University of S?o Carlos, P.O. Box 676, CEP 13565-905, S?o Carlos - SP, Brazil
2. Chemistry Division of Institute for Technological Research - IPT, P. O. Box 7141, CEP 01064 - 970, S?o Paulo - SP, Brazil
Abstract:A new process to produce defluorinated dicalcium phosphate (DCP) using phosphate rock concentrate has been developed. This new process has as main characteristic the low concentration of P2O5 in the liquid phase. The process comprises three main steps: solubilization of the phosphate rock concentrate with sulfuric acid, defluorination of the phosphoric acid solution with potassium sulfate and neutralization of the phosphoric acid solution with calcium hydroxide. The P2O5 precipitated in the pH range between 2.00 and 5.00 consisted basically of anhydrous dicalcium phosphate. This revised version was published online in August 2006 with corrections to the Cover Date.
Keywords:animal food  dicalcium phosphate  mineralsupplement  phosphate rock  solubilization
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