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[(Bi_(1-x-y)La_x)Na_(1-y)]_(0.5)Ba_yTiO_3压电陶瓷的性能与微结构
引用本文:赁敦敏,肖定全,朱建国,余萍,庄严.[(Bi_(1-x-y)La_x)Na_(1-y)]_(0.5)Ba_yTiO_3压电陶瓷的性能与微结构[J].电子元件与材料,2004,23(11):1-3.
作者姓名:赁敦敏  肖定全  朱建国  余萍  庄严
作者单位:1. 四川大学材料科学与工程学院材料科学系,四川,成都,610064
2. 广州杰赛科技股份有限公司,广东,广州,510310
基金项目:国家自然科学基金,国家自然科学基金,国家高技术研究发展计划(863计划),高等学校博士学科点专项科研项目,50410179,59972020,2001-AA325060,20030610035,,,,
摘    要:针对钛酸铋钠(Bi0.5Na0.5TiO3)基无铅压电铁电材料,提出了新型的ABO3型A位多重复合无铅压电陶瓷体系(Bi1-x-yLax)Na1-y]0.5BayTiO3;利用传统陶瓷工艺和电子陶瓷公司生产中使用的原料,制备了该体系陶瓷;研究了该陶瓷的压电性质与微观结构。研究结果表明,该体系陶瓷具有单相钙钛矿结构;其压电常数d33可达183 pC/N,其机电耦合系数kp可达0.355;适量La3+对Bi3+的取代改善了压电性能;在1 175℃,2 h的烧结条件下,能够获得致密的(Bi1-x-yLax)Na1-y]0.5BayTiO3陶瓷;La3+的引入抑制了晶粒的生长,高La含量的陶瓷晶粒较小。

关 键 词:电子技术  钛酸铋钠  无铅压电陶瓷  压电性质  微观结构
文章编号:1001-2028(2004)11-0001-03
修稿时间:2004年8月26日

Studies on the Properties and Microstructures of [(Bi1-x-yLax)Na1-y]0.5BayTiO3 Lead-free Piezoelectric Ceramics
LIN Dun-min,XIAO Ding-quan,ZHU Jian-guo,YU Ping,ZHUANG Yan.Studies on the Properties and Microstructures of [(Bi1-x-yLax)Na1-y]0.5BayTiO3 Lead-free Piezoelectric Ceramics[J].Electronic Components & Materials,2004,23(11):1-3.
Authors:LIN Dun-min  XIAO Ding-quan  ZHU Jian-guo  YU Ping  ZHUANG Yan
Affiliation:LIN Dun-min1,XIAO Ding-quan1,ZHU Jian-guo1,YU Ping1,ZHUANG Yan2
Abstract:New (Bi1-x-yLax)Na1-y]0.5BayTiO3 lead-free piezoelectric ceramics were developed based on the design of the multiple complex in the A-site of ABO3-type Bi0.5Na0.5TiO3 ferroelectrics, and the ceramics were prepared by the conventional ceramic sintering technique. Piezoelectric properties,dielectric properties and microstructures of (Bi1-x-yLax)Na1-y]0.5BayTiO3 lead-free piezoelectric ceramics were also studied. The measurements of piezoelectric properties reveal that this systems provides a high piezoelectric performance: d33=183pC/N,kp=0.355. The ceramics were well sintered at 1175℃ for 2 hours. La3+ suppresses the growing up of grains, and the size of those grains of the ceramics with high La3+ concentration is smaller than that with low La3+ concentration.
Keywords:electronic technology  [(Bi1-x-yLax)Na1-y]0  5BayTiO3  lead-free piezoelectric ceramics  piezoelectric properties  microstructure
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