| 降冰片烯加成聚合催化剂的研究进展 |
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| 引用本文： | 孙文华,杨海健,徐桂云,张红江,东升魁.降冰片烯加成聚合催化剂的研究进展[J].石油化工,2004,33(1):76-81. |
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| 作者姓名： | 孙文华 杨海健 徐桂云 张红江 东升魁 |
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| 作者单位： | 1. 中国科学院化学研究所,分子科学中心工程塑料国家重点实验室,北京,100080
2. 中国石油天然气股份有限公司,吉林石化分公司石化研究院,吉林,吉林,132021 |
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| 摘 要： | 按照催化剂中心金属的类型,综述了降冰片烯加成聚合催化剂的发展和催化体系的特点。降冰片烯加成聚合催化剂分为3类:前过渡金属钛和锆催化剂;后过渡金属钯和镍催化剂;铬、钴、钒和稀土金属等催化剂。在介绍了文献工作的基础上,对中科院化学研究所在镍配合物催化降冰片烯聚合领域的研究结果进行了简单的总结,阐述了这类镍催化剂的简易合成和结构特点,以及催化条件变化对产物性能的影响。
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| 关 键 词： | 降冰片烯 加成聚合 催化剂 |
| 文章编号： | 1000-8144(2004)01-0076-06 |
| 修稿时间： | 2003年7月14日 |
Progress of Catalysts for Vinyl - Polymerization of Norbornene |
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| Sun Wenhua,Yang Haijian,Xu Guiyun,Zhang Hongjiang,Dong Shengkui.Progress of Catalysts for Vinyl - Polymerization of Norbornene[J].Petrochemical Technology,2004,33(1):76-81. |
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| Authors: | Sun Wenhua Yang Haijian Xu Guiyun Zhang Hongjiang Dong Shengkui |
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| Affiliation: | Sun Wenhua~1,Yang Haijian~1,Xu Guiyun~1,Zhang Hongjiang~2,Dong Shengkui~2,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China,2.Research and Development Department,Jilin Petrochemical Company,PetroChina Company Limited,Jilin Jilin 132021,China) |
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| Abstract: | Poly(norbornene) as novel engineering plastics has attracted great attention of chemists and engineers because of its various applications as thermostable,optical,dielectric and photoresist polymers.To promote Chinese academic and industrial consideration of poly(norbornene),the current review covers catalysts for vinyl-polymerization of norbornene in three types according to active metallic centers:early-transition Ti and Zr metals,late-transition Pd and Ni metals,and others metals.In addition,a series of novel nickel catalysts were easily prepared and showed high activity for vinyl polymerization of norbornene.A bright future of this project is expected,and poly(norbornene) will be important engineering plastics in future material science. |
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| Keywords: | norbornene vinylic polymerization catalyst |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
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