| 间硝基苯甲醛肟氧基乙酸的合成 |
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| 引用本文： | 刘春玲,魏雪梅,李微,邵玉兵.间硝基苯甲醛肟氧基乙酸的合成[J].吉林师范大学学报（自然科学版）,2012(2):113-115. |
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| 作者姓名： | 刘春玲 魏雪梅 李微 邵玉兵 |
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| 作者单位： | 吉林师范大学化学学院 |
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| 基金项目： | 吉林省教育厅“十一五”科学技术研究项目(吉教科合字2010第354号);四平市科技发展计划项目(四科合字第2010002号) |
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| 摘 要： | 间硝基苯甲醛肟与氯乙酸在乙腈中反应生成间硝基苯甲醛肟氧基乙酸.探讨了反应物的物料比、反应时间等因素对产品产率的影响.实验表明:以乙腈为溶剂,n(间硝基苯甲醛肟):n(氯乙酸):n(氢氧化钠)=1∶1.1∶2.2,反应时间为4 h的优化条件下,间硝基苯甲醛肟氧基乙酸的产率达到62.7%.
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| 关 键 词： | 间硝基苯甲醛肟 氯乙酸 间硝基苯甲醛肟氧基乙酸 |
Synthesis of m-Nitrobenzylideneaminooxy Acetic Acid |
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| LIU Chun-ling,WEI Xue-mei,LI Wei,SHAO Yu-bing.Synthesis of m-Nitrobenzylideneaminooxy Acetic Acid[J].Jilin Normal University Journal(Natural Science Edition),2012(2):113-115. |
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| Authors: | LIU Chun-ling WEI Xue-mei LI Wei SHAO Yu-bing |
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| Affiliation: | (College of Chemistry,Jilin Normal University,Siping 136000,China) |
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| Abstract: | The target compound was synthesized with m-nitrobenzaldehyde oxime and chloroacetic acid in acetonitrile.The influence of the factors of molar ratio of the reagent,the reaction time on the product yield was discussed.The experimental results show that when the molar ratio of n(m-nitrobenzaldehyde):n(chloroacetic acid):n(sodium hydroxide)is 1:1.1:2.2,and the reaction time is 4 h,the yield can reach 62.7%. |
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| Keywords: | m-nitrobenzaldehyde oxime chloroacetic acid m-nitrobenzylideneaminooxy acetic acid |
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