| 祁州漏芦蜕皮甾酮类化学成分的研究 |
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| 引用本文： | 果德安,楼之岑,高从元,乔梁,彭嘉柔.祁州漏芦蜕皮甾酮类化学成分的研究[J].药学学报,1991,26(6):442-446. |
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| 作者姓名： | 果德安 楼之岑 高从元 乔梁 彭嘉柔 |
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| 作者单位： | 北京医科大学药学院，北京医科大学药学院，北京医科大学分析计算中心，北京医科大学分析计算中心，北京医科大学分析计算中心 北京 100083，北京 100083，北京 100083，北京 100083，北京 100083 |
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| 摘 要： | 从祁州漏芦Rhaponticum uniflorum(L.)DC.]的根中,分离出三个蜕皮甾酮类化合物Ⅰ,Ⅱ,Ⅲ,其中Ⅱ根据UV,IR,MS,13CNMR,1HNMR,1H-1HCOSY,1H-1HNOESY,1H-13C COSY,及CD谱确定其结构为(20R,22R,24S)-2β,3β,11α,14α,20,22,24-heptahydroxy-5β-cholest-7-en-6-one,为一新化合物,命名为漏芦甾酮(rhaponfisterone)。化合物Ⅰ和Ⅲ分别鉴定为蜕皮甾酮(ecdysterone)和土克甾酮(turkesterone)。
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| 关 键 词： | 祁州漏芦 蜕皮甾酮 漏芦甾酮 土克甾酮 |
| 收稿时间： | 1990-05-07 |
PHYTOECDYSTEROIDS OF RHAPONTICUM UNIFLORUM ROOT |
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| DA Guo,ZC Lou,CY Gao,L Qiao and JR Peng.PHYTOECDYSTEROIDS OF RHAPONTICUM UNIFLORUM ROOT[J].Acta Pharmaceutica Sinica,1991,26(6):442-446. |
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| Authors: | DA Guo ZC Lou CY Gao L Qiao and JR Peng |
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| Affiliation: | School of Pharmaceutical Sciences, Beijing Medical University. |
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| Abstract: | Three phytoecdysteroids I, II and III were isolated from the root of Rhaponticum uniflorum (L.) DC. and their structures were elucidated by chemical and spectroscopic methods (UV, IR, EI-MS, FAB-MS, 1HNMR, 13CNMR, 1H-1H COSY, 1H-1H NOESY, 1H-13CCOSY and CD). Compound II is new and named rhapontisterone, its structure was confirmed as (20R, 22R, 24S)-2 beta, 3 beta, 11 alpha, 14 alpha, 20, 22, 24-heptahydroxy-5 beta cholest-7-en-6-one. The other two, I and III, were identified as ecdysterone and turkesterone, respectively, both are known compounds, but turkesterone was isolated for the first time from the title plant. |
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| Keywords: | Rhaponticum uniflorum (L )DC Ecdysterone Rhapontisterone Turkesterone |
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