Optical properties of Eu^2+-doped strontium borate glasses containing F-and Li^+ ions |
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引用本文: | 黄彦林,张基完,王锡钢,姜传芳.Optical properties of Eu^2+-doped strontium borate glasses containing F-and Li^+ ions[J].中国稀土学报(英文版),2008,26(4):490-494. |
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作者姓名: | 黄彦林 张基完 王锡钢 姜传芳 |
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作者单位: | [1]School of Material Engineering, Soochow University, Suzhou 215021, China;; [2]Department of Physics, Changwon National University, Changwon 641-773, Republic of Korea |
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基金项目: | Project supported by Jiangsu Provincial Natural Science Foundation of China (BK-2007053), and the Second Stage of Brain Korea 21 Project Corporations at Changwon National University |
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摘 要: | In this experiment, strontium borate glasses were prepared using the conventional quenching method in air atmosphere. Optical absorption, photoluminescence excitation and emission spectra, X-ray excited luminescence (XEL), and luminescence decay curve of the as-prepared glasses were investigated at room temperature. The as-prepared glasses had two kinds of Eu ions, i.e., Eu^2+ and Eu^2+. Compared with the reported results of strontium borate glasses, Eu^2+ luminescence was enhanced in the studied strontium borate glasses coprepared with F^- and Li^+ ions. The coexisting of Li^+ or F^- in the borate glasses could create more negative defect Vsr″ and stabilize Eu^2+ ions, which might act as donor of electrons; For the F^- doping, the new center of B(O, F)4 (or BO3F) and BO2F2 units could be considered to be the distorted (BO4), which were needed as a rigid framework to stabilize the divalent rare earth ions.
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关 键 词: | 非晶体材料 玻璃 铕 发光性 稀土 |
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