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不同铝粉含量RDX基浇注PBX炸药的慢速烤燃特性研究
引用本文:高立龙,李昆,陈春燕,郑亚峰,南海,王晓峰.不同铝粉含量RDX基浇注PBX炸药的慢速烤燃特性研究[J].科学技术与工程,2018,18(6).
作者姓名:高立龙  李昆  陈春燕  郑亚峰  南海  王晓峰
作者单位:西安近代化学研究所,西安近代化学研究所,西安近代化学研究所,西安近代化学研究所,西安近代化学研究所,西安近代化学研究所
摘    要:通过差式扫描量热法(DSC)测定不同比例Al/RDX浇注PBX炸药的热分解过程,分别获得不同升温速率下的热分解峰温,根据Kissinger方程计算了其表观活化能,分析了表观活化能与Al/RDX比例的关系。采用实验室慢速烤燃试验,获取了不同Al/RDX比例配方的响应特性。结果表明,Al/RDX比例与配方表观活化能及慢速烤燃响应特性有关,Al含量为15%时,表观活化能最小,发生慢速烤燃响应的时间最早,但是响应剧烈程度最低。

关 键 词:浇注PBX  铝粉含量  活化能  慢速烤燃
收稿时间:2017/4/20 0:00:00
修稿时间:2017/6/13 0:00:00

The Study of the Slow Cook-off Test Response Characterization of Different Al/RDX Ratio Cast PBX
Gao Li-long,Chen Chun-yan,Zheng Ya-feng,Nan Hai and Wang Xiao-feng.The Study of the Slow Cook-off Test Response Characterization of Different Al/RDX Ratio Cast PBX[J].Science Technology and Engineering,2018,18(6).
Authors:Gao Li-long  Chen Chun-yan  Zheng Ya-feng  Nan Hai and Wang Xiao-feng
Abstract:The decomposition of the cast PBX with different proportions of Al/RDX were determined by differential scanning calorimetry(DSC), and the decomposition kinetic parameters(activation energy, Ea) were calculated by means of kissinger equation. The relationship of Ea and Al/RDX ratio were analysed. The response characterization of different Al/RDX ratio were studied by the laboratory slow cook-off test. The results showed that the activation energy and the slow cook-off characteristics were related to the Al/RDX ratio. The activation energy was the smallest, and the time of the slow cook-off response was the earliest, but the response intensity was the lowest when the Al content was 15%.
Keywords:cast PBX  al content  activation energy  slow cook-off
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