| 二维层状铜配位聚合物[Cu2(TFBDC)2(DMF)2]2·3MeOH·2DMF的合成、晶体结构和磁性(TFBDC=四氟对苯二甲酸根；DMF=N，N-二甲基甲酰胺) |
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| 引用本文： | 朱恩静,刘 琦,陈 群,何明阳,陈圣春,黄鹤翔,杨 骞.二维层状铜配位聚合物[Cu2(TFBDC)2(DMF)2]2·3MeOH·2DMF的合成、晶体结构和磁性(TFBDC=四氟对苯二甲酸根；DMF=N，N-二甲基甲酰胺)[J].无机化学学报,2008,24(9):1428-1433. |
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| 作者姓名： | 朱恩静 刘 琦 陈 群 何明阳 陈圣春 黄鹤翔 杨 骞 |
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| 作者单位： | 江苏工业学院化学化工学院,江苏省精细石油化工重点实验室,常州,213164 |
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| 基金项目： | 国家自然科学基金，江苏省教育厅自然科学基金，江苏省精细石油化工重点实验室科学基金，江苏省科技创新团队资助项目 |
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| 摘 要： | 由Cu(Ⅱ)的硝酸盐与四氟对苯二甲酸(H2tfbdc)的自组装得到标题配合物.用元素分析、红外光谱、热重分析、X-衍射单晶结构分析等对其进行了表征.晶体结构表明,标题配合物的晶体属单斜晶系,空间群为C2/c,晶胞参数:a=3.3739(5)nm,b=1.5696(2)am,c=1.641 9(2)nm,β=1 17.527(2)°.每个铜离子与来自4个四氟对苯二甲酸分子的4个氧原子和1个N,N-二甲基甲酰胺分子中的氧原子配位,形成四方锥的配位构型.四氟对苯二甲酸根桥连铜离子形成具有孔穴的二维层状结构,相邻的层状结构又通过氢键形成三维的超分子网络结构.配合物中一些苯环上的-CF基团具有无序结构.变温磁化率数据(300～1.8 K)显示配合物中分别存在反铁磁性和铁磁性相互作用.
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| 关 键 词： | 铜 配位聚合物 四氟对苯二甲酸 晶体结构 磁性 |
Synthesis, Crystal Structure and Magnetic Property of 2D layer Copper Coordination Compound [Cu2(TFBDC)2(DMF)2]2·3MeOH·2DMF (TFBDC=tetrafluoroterephthalate;DMF=N,N-dimethyl formamide) |
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| ZHU En-Jing,LIU Qi,CHEN Qun,HE Ming-Yang,CHEN Sheng-Chun,HUANG He-Xiang and YANG Qian.Synthesis, Crystal Structure and Magnetic Property of 2D layer Copper Coordination Compound [Cu2(TFBDC)2(DMF)2]2·3MeOH·2DMF (TFBDC=tetrafluoroterephthalate;DMF=N,N-dimethyl formamide)[J].Chinese Journal of Inorganic Chemistry,2008,24(9):1428-1433. |
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| Authors: | ZHU En-Jing LIU Qi CHEN Qun HE Ming-Yang CHEN Sheng-Chun HUANG He-Xiang and YANG Qian |
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| Affiliation: | School of Chemistry and Chemical Engineering and Jiangsu Province Key Laboratory of Fine Petro-chemical Technology, Jiangsu Polytechnic University, Changzhou, Jiangsu 213164,School of Chemistry and Chemical Engineering and Jiangsu Province Key Laboratory of Fine Petro-chemical Technology, Jiangsu Polytechnic University, Changzhou, Jiangsu 213164,School of Chemistry and Chemical Engineering and Jiangsu Province Key Laboratory of Fine Petro-chemical Technology, Jiangsu Polytechnic University, Changzhou, Jiangsu 213164,School of Chemistry and Chemical Engineering and Jiangsu Province Key Laboratory of Fine Petro-chemical Technology, Jiangsu Polytechnic University, Changzhou, Jiangsu 213164,School of Chemistry and Chemical Engineering and Jiangsu Province Key Laboratory of Fine Petro-chemical Technology, Jiangsu Polytechnic University, Changzhou, Jiangsu 213164,School of Chemistry and Chemical Engineering and Jiangsu Province Key Laboratory of Fine Petro-chemical Technology, Jiangsu Polytechnic University, Changzhou, Jiangsu 213164 and School of Chemistry and Chemical Engineering and Jiangsu Province Key Laboratory of Fine Petro-chemical Technology, Jiangsu Polytechnic University, Changzhou, Jiangsu 213164 |
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| Abstract: | |
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| Keywords: | copper coordination compound tetrafluoroterephthalatic acid crystal structure magnetic property |
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