| 不同氧化剂对黄县油页岩氧化的影响 |
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| 引用本文： | 陆绍信,王廷芬.不同氧化剂对黄县油页岩氧化的影响[J].中国石油大学学报(自然科学版),1987(1). |
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| 作者姓名： | 陆绍信 王廷芬 |
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| 作者单位： | 华东石油学院北京研究生部
(陆绍信)，华东石油学院北京研究生部(王廷芬) |
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| 摘 要： | 采用三种不同类型的氧化剂对黄县油页岩进行氧化。试验结果表明,采用H_2O_2 TFA(三氟醋酸)作氧化剂时,黄县油页岩中干酪根的芳构部分优先被氧化;用 KMnO_4 作氧化剂时,黄县油页岩中干酪根的脂族结构部分优先被氧化;当用空气作氧化剂时,黄县油页岩中干酪根的芳构部分和脂族结构部分同时被氧化。在碱性介质下,常压空气可以直接氧化黄县油页岩,无明显的氧化选择性。
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| 关 键 词： | 油页岩 氧化剂 三氟乙酸 高锰酸钾 干酪根 |
EFFECT OF DIFFERENT OXIDANTS ON THE OXIDATION OF HUANGXIAN OIL SHALE |
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| Lu Shaoxin Wang Tingfen.EFFECT OF DIFFERENT OXIDANTS ON THE OXIDATION OF HUANGXIAN OIL SHALE[J].Journal of China University of Petroleum,1987(1). |
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| Authors: | Lu Shaoxin Wang Tingfen |
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| Affiliation: | Lu Shaoxin Wang Tingfen |
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| Abstract: | Huangxian oil shale was oxidated by three different oxidants. The results show that the aromatic moiety of kerogen in Huangxian oil shale was preferentially oxidated by using H2O2 TFA (trifluoroacetic acid) as an oxidant and the aliphatic moiety of kerogen in Huangxian oil shale was preferentially oxidated by using KMnO4 as an oxidant. By using air as an oxidant, the aromatic moiety of kerogen and the aliphatic moiety of kerogen in Huangxian oil shale were simultaneously oxidated. In alkline medium Huangxian oil shale can be directly oxidated by air. |
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| Keywords: | Oil shales Oxidant Trifluoroacetic acid Potassium per-manganate Kerogen |
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