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聚四氟乙烯膜的表面改性研究
引用本文:孙晓宁,王成群.聚四氟乙烯膜的表面改性研究[J].辽宁化工,2007,36(7):439-442.
作者姓名:孙晓宁  王成群
作者单位:西安工程大学,陕西,西安,710048
基金项目:陕西省科技厅科学技术研究发展计划项目(国际合作)
摘    要:利用氩等离子体对聚四氟乙烯膜进行预处理,经与空气接触后接枝丙烯酸。用碘化钠法测定了膜表面过氧基团的浓度,探讨了等离子体处理时间、放电功率对膜表面过氧基团浓度的影响;过氧基团的浓度对接枝率的影响。利用红外光谱和X射线光电子能谱图鉴定了接枝产物,对改性后薄膜的表面亲水性进行了测试。

关 键 词:等离子体  聚四氟乙烯膜  过氧基团浓度  丙烯酸  接枝
文章编号:1004-0935(2007)07-0439-04
修稿时间:2007-03-15

Study on Surface Modification of Polytetrafluoroethylene Film
SUN Xiao-ning,WANG Chen-qun.Study on Surface Modification of Polytetrafluoroethylene Film[J].Liaoning Chemical Industry,2007,36(7):439-442.
Authors:SUN Xiao-ning  WANG Chen-qun
Abstract:In this study,the Polytetrafluoroethylene(PTFE) film was pre-treated by argon plasma and contacted with air before graft with acrylic acid.Iodide method was used to determine the concentration of peroxide on the surface.It was discussed that the effect of plasma treating time and power of discharge on the peroxide concentration of PTFE surface,and that the effect of the peroxide concentration on grafting ratio.The grafted product was detected with FTIR spectra and XPS.Surface hydrophilic ability of the grafted film was tested.
Keywords:Argon plasma  Polytetrafluoroethylene film  Peroxide concentration  Acrylic acid  Grafting
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