Participation of lewis base on vinyl chloride polymerization with catalyst system |
| |
Authors: | Akira Akimoto |
| |
Affiliation: | Central Research Laboratory, Toyo Soda Manufacturing Co. Ltd, Yamaguchi-ken, Japan |
| |
Abstract: | The polymerization of vinyl chloride has been investigated using an catalyst system in the presence of various Lewis bases. Effective Lewis bases are γ-butyrolactone, diglyme and diethylenetriamine which are multidentate. The rate of polymerization is dependent not only on the basicity of the Lewis base used but also on a coordination number of one. The latter is the predominant factor. For the effect of polymeric amines, a tentative hypothesis is discussed. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|