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川东南五峰组—龙马溪组页岩气录井碳同位素特征及其地质意义
引用本文:牛强,张焕旭,朱地,徐志尧,仰云峰,丁安徐,高和群,张立生.川东南五峰组—龙马溪组页岩气录井碳同位素特征及其地质意义[J].天然气地球科学,2020,31(9):1294-1305.
作者姓名:牛强  张焕旭  朱地  徐志尧  仰云峰  丁安徐  高和群  张立生
作者单位:1.中国石化工程公司胜利地质录井公司,山东 东营 257000;2.苏州冠德能源科技有限公司,江苏 苏州 215004;3.苏州加州能源与环境研究院有限公司,江苏 苏州 215004;4.齐鲁工业大学(山东省科学院),山东省科学院能源研究所,山东省生物质气化技术重点实验室,山东 济南 250000;5.中国石化华东油气田分公司,江苏 扬州 225000
基金项目:国家科技重大专项“地震与井筒精细勘探关键技术”(2016ZX05006-002);中国石油勘探开发研究院科学研究与技术开发项目“古老层系页岩气同位素实时检测及含气性模型”(2018ycq01)
摘    要:为了更详尽地分析不同深度段五峰组—龙马溪组页岩气的碳同位素特征以及页岩气的成藏富集规律,选取川东南地区3口典型页岩气评价井开展了页岩气碳同位素录井工作。在钻探现场连续取样并检测泥浆气的碳同位素值,并以DY5井为例检测了岩屑释气过程中的碳同位素变化。基于碳同位素录井数据,综合分析了五峰组—龙马溪组页岩气的碳同位素平面分布及纵向变化特征、碳同位素倒转特征和岩屑释气过程中的碳同位素分馏特征。综合分析认为:四川盆地五峰组—龙马溪组页岩气碳同位素值由盆地周缘向中心逐渐变轻,这一变化规律主要受控于页岩的热演化程度;川东南3口井的泥浆气碳同位素的纵向变化及倒转特征具有一定共性,表明其具有相近的页岩气富集规律;DY5井的岩屑罐顶气越靠近地质甜点区域同位素分馏越明显且岩屑释气量越大,反映该段页岩气具有初始地层压力高、含气量大、纳米孔隙更发育等特征。

关 键 词:页岩气  碳同位素录井  碳同位素倒转  页岩气富集规律  碳同位素分馏  
收稿时间:2020-01-06

Mud gas isotopic logging of Wufeng-Longmaxi shale in southeastern Sichuan Basin
Qiang NIU,Huan-xu ZHANG,Di ZHU,Zhi-yao XU,Yun-feng YANG,An-xu DING,He-qun GAO,Li-sheng ZHANG.Mud gas isotopic logging of Wufeng-Longmaxi shale in southeastern Sichuan Basin[J].Natural Gas Geoscience,2020,31(9):1294-1305.
Authors:Qiang NIU  Huan-xu ZHANG  Di ZHU  Zhi-yao XU  Yun-feng YANG  An-xu DING  He-qun GAO  Li-sheng ZHANG
Affiliation:1.Geological Logging Company, SINOPEC Shengli Petroleum Engineering Co. Ltd. , Dongying 257000, China;2.Suzhou Grand Energy Technology Co. Ltd. , Suzhou 215004, China;3.Suzhou California Energy and Environment Research Institute Co. Ltd. , Suzhou 215004, China;4.Energy Institute, Qilu University of Technology (Shandong Academy of Sciences),Shandong Provincial Key Laboratory of Biomass Gasification Technology, Ji’nan 250000, China;5.SINOPEC East China Oil and Gas Company, Yangzhou 225000, China
Abstract:In order to analyze the carbon isotope characteristics of shale gas from the Wufeng-Longmaxi formations at different depths in more detail, and research the shale gas accumulation, three typical shale gas evaluation wells in southeastern Sichuan Basin were selected to carry out carbon isotope logging. The carbon isotope of mud gas was continuously sampled and measured with drilling, and the carbon isotope change during the gas release from cuttings was also measured. Based on data obtained from the isotope logging, the carbon isotope distribution and vertical variation, as well as the carbon isotope reversal and carbon isotope fractionation of shale gas are comprehensively analyzed, which reveals that the carbon isotope value of Wufeng-Longmaxi shale gas in the Sichuan Basin gradually decreases from the margin to the center of the basin, and this change is mainly controlled by the maturity of the organic matter. The carbon isotope characteristics of shale gas of these three wells have certain commonality, which indicates that shale gas accumulation rules were similar in this area. In sweet point, the carbon isotope fractionation of the top gas of the cuttings jar is much greater, and the amount of gas released from the cuttings is higher, reflecting this section has high initial pressure, large gas content, and more nano pores.
Keywords:Shale gas  Isotope logging  Reversal of carbon isotope  Shale gas accumulation rules  Carbon isotope fractionationFoundation items:The National Science and Technology Major Project(Grant No  2016ZX05006-002)  The Scientific Research and Technological Development Project of RIPED(Grant No  2018ycq01)  
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