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Photocatalytic remediation of γ-hexachlorocyclohexane contaminated soils using TiO2 and montmorillonite composite photocatalyst
Authors:ZHAO Xu  QUAN Xie  CHEN Shuo  ZHAO Hui-min  LIU Yu
Abstract:TiO2 and montmorillonite composite photocatalysts were prepared and applied in degrading γ-hexachlorocyclohexane(γ-HCH)in soils.After being spiked with γ-HCH,soil samples loaded with the composite photocatalysts were exposed to UV-light irradiation.The results indicated that the photocatalytic activities of the composite photocatalysts varied with the content of TiO2 in the order of 10%<70%<50%<30%.Moreover,the photocatalytic activity of the composite photocatalysts with TiO2 content 30% was higher than that of the pure P25 with the same mass of TiO2.The strong adsorption capacity of the composite photocatalysts and quantum size effect may contribute to its increased photocatalytic activities.In addition,effect of dosage of composite photocatalysts and soil pH on γ-HCH photodegradation was investigated. Pentachlorocyclohexene,trichlorocyclohexene,and dichlorobenzene were detected as photodegradation intermediates,which were gradually degraded with tlle phOtOdegradation evolution.
Keywords:TiO2  montmorillonite  γ-HCH  soil surfaces  composite photocatalysts  remediation  Photocatalytic  photocatalyst  composite  montmorillonite  soils  gradually  evolution  intermediates  photodegradation  quantum size effect  dosage  soil pH  addition  strong  adsorption capacity  increased  photocatalytic activity  pure  mass
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