| 基团转移聚合反应中的有机硅引发剂 |
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| 引用本文： | 严微,黄世强,程时远.基团转移聚合反应中的有机硅引发剂[J].有机硅材料,2005,19(3):27-32,54. |
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| 作者姓名： | 严微 黄世强 程时远 |
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| 作者单位： | 湖北大学化学与材料科学学院,武汉,430062 |
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| 摘 要： | 评述了近年来基团转移聚合反应中几种常用的有机硅引发剂(如单官能团引发剂、双官能团引发剂、其它乙烯酮硅烷缩醛引发剂、大分子引发剂及其它含硅引发剂)的研究进展,并展望了基团转移聚合反应在高分子合成中的重要作用及应用前景。
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| 关 键 词： | 基团转移聚合 乙烯酮硅烷缩醛类化合物 含硅引发剂 甲基丙烯酸酯 嵌段共聚物 |
| 文章编号： | 1009-4369(2005)02-0027-06 |
Silicone initiator in group transfer polymerization reaction |
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| YAN Wei,HUANG Shi-qing,CHENG Shi-yuan.Silicone initiator in group transfer polymerization reaction[J].Silicone Material,2005,19(3):27-32,54. |
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| Authors: | YAN Wei HUANG Shi-qing CHENG Shi-yuan |
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| Abstract: | The recent development of several kinds of typical silicone initiators,i.e.monofunctional radical initiators,difunctional radical initiators,other silicon-containing initiators and macroinitiators,in the reaction of group transfer polymerization (GTP) were introduced,and the vital function and application prospect of group transfer polymerization in the synthesis of macromonomer were expected. |
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| Keywords: | group transfer polymerization (GTP) silicone silicon-containing initiator compound methacrylate block copolymer |
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