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生物柴油-乙醇-水三元体系及其乳化试验研究
引用本文:周后波,曹阳,李进,郑竹,张可喜.生物柴油-乙醇-水三元体系及其乳化试验研究[J].精细石油化工,2013,30(3):63-66.
作者姓名:周后波  曹阳  李进  郑竹  张可喜
作者单位:海南大学材料与化工学院,海南海口,570228
基金项目:海南省国际重点科技合作项目,海口市重点项目,海南大学校青年基金
摘    要:研究了生物柴油-乙醇-水三元稳定体系中的最大含水量,分析了生物柴油-乙醇-水三元体系的相行为,得到了稳定的单相区和两相区。考察了不同乳化剂、乳化剂质量分数以及乙醇的含量对体系含水量的影响,结果表明:在乳化剂中m(油酸)∶m(壬基酚聚氧乙烯醚)=3∶7,乳化剂用量为油重的15%,乙醇用量为油重的40%时,体系含水量可达8.82%。

关 键 词:生物柴油  乙醇  相图  含水量  乳化

STUDY OF BIODIESEL-ETHANOL-WATER SYSTEM AND ITS EMULSIFICATION
Zhou Houbo , Cao Yang , Li Jin , Zheng Zhu , Zhang Kexi.STUDY OF BIODIESEL-ETHANOL-WATER SYSTEM AND ITS EMULSIFICATION[J].Speciality Petrochemicals,2013,30(3):63-66.
Authors:Zhou Houbo  Cao Yang  Li Jin  Zheng Zhu  Zhang Kexi
Affiliation:(School of Materials and Chemical Engineering,Hainan University,Haikou570288,Hainan,China)
Abstract:To get the stable system of biodiesel-ethanol-water,high quality biodiesel was prepared,and the phase behavior of biodiesel-ethanol-water system was researched by measuring the most moisture content of the stable system,the result indicated that there existed a single-phase region and twophase region in the phase diagram.The effect on moisture content was investigated under different emulsifiers,emulsifier content and the content of ethanol.The result indicates that the optimum condition in the experiment is as follows.The emulsifier is the blend of oleic acid and nonylphenol polyoxyethylene ether,the mass ratio of oleic acid and nonylphenol polyoxyethylene ether is 3∶7,the dosage of emulsifier and ethanol are 15%and 40% of the weight of biodiesel respectively,the moisture content can reach 8.82%.
Keywords:biodiesel  ethanol  phase diagram  moisture content  emulsification
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