| Effect of surfactants on preparation of nanometer TiO2 by pyrohydrolysis |
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| 作者姓名： | 柴立元 于延芬 张刚 彭兵 韦顺文 |
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| 作者单位： | School of Metallurgical Science and Engineering Central South University，School of Metallurgical Science and Engineering，Central South University，School of Metallurgical Science and Engineering，Central South University，School of Metallurgical Science and Engineering，Central South University，School of Metallurgical Science and Engineering，Central South University，Changsha 410083，China，Changsha 410083，China Changsha Environmental Protection College，Changsha 410004，China，Changsha 410083，China，Changsha 410083，China，Changsha 410083，China |
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| 基金项目： | Project（04GK2007） supported by the Key Project of Science and Technology Plan of Hunan Province, China |
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| 摘 要： | The nanometer TiO2 was prepared by pyrohydrolysis with titanic solution.The effects of species and content of the surfactants on the particle size,morphology and phase of TiO2 were studied by using LPA,XRD and TEM respectively.The results show that it is beneficial to reducing the aggregation of TiO2 particles with adding surfactants to the solution.Nanometer TiO2 powders with the size of 40-55 nm are obtained by adding the anion surfactants in the optimal content of 1.5%(mass fraction).The effect of cationic surfactant for reducing particle aggregation is not as good as that of anion.The crystal phase constitutent of TiO2 is dependent on the temperature of thermal treatment and complete anatase can be achieved after calcining in the temperature range of 350-750℃.
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| 关 键 词： | 二氧化钛 热水解工艺 粉末合金 物化性质 |
| 收稿时间： | 2006-06-23 |
| 修稿时间： | 2006-10-26 |
Effect of surfactants on preparation of nanometer TiO2 by pyrohydrolysis |
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| CHAI Li-yuan,YU Yan-fen,ZHANG Gang,PENG Bing,WEI Shun-wen.Effect of surfactants on preparation of nanometer TiO2 by pyrohydrolysis[J].Transactions of Nonferrous Metals Society of China,2007,17(1):176-180. |
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| Authors: | CHAI Li-yuan YU Yan-fen ZHANG Gang PENG Bing WEI Shun-wen |
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| Affiliation: | 1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China;2. Changsha Environmental Protection College, Changsha 410004, China |
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| Abstract: | The nanometer TiO2 was prepared by pyrohydrolysis with titanic solution. The effects of species and content of the surfactants on the particle size, morphology and phase of TiO2 were studied by using LPA, XRD and TEM respectively. The results show that it is beneficial to reducing the aggregation of TiO2 particles with adding surfactants to the solution. Nanometer TiO2 powders with the size of 40–55 nm are obtained by adding the anion surfactants in the optimal content of 1.5% (mass fraction). The effect of cationic surfactant for reducing particle aggregation is not as good as that of anion. The crystal phase constitutent of TiO2 is dependent on the temperature of thermal treatment and complete anatase can be achieved after calcining in the temperature range of 350–750 °C. |
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| Keywords: | surfactant nanometer TiO2 pyrohydrolysis |
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