| 微波辐射下硫酸铁催化合成乙酸环己酯 |
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| 引用本文： | 陈小原,杨勇,章爱华.微波辐射下硫酸铁催化合成乙酸环己酯[J].吉首大学学报(自然科学版),2008,29(4):71-74. |
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| 作者姓名： | 陈小原 杨勇 章爱华 |
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| 作者单位： | （吉首大学化学化工学院，湖南 吉首 416000） |
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| 摘 要： | 在微波辐射下，以水合硫酸铁作催化剂，快速合成了乙酸环己酯，确定了酯化的最佳条件.实验结果表明，最佳酯化条件为：微波功率640 W，醇酸物质的量比1.4∶1，带水剂用量6 mL，催化剂用量1.0 g，反应时间30 min.在最佳条件下酯化率（以乙酸计）可达91.6%.
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| 关 键 词： | 微波辐射 水合硫酸铁 乙酸环己酯 |
Synthesis of Cydohexyl Acetate Catalyzed by Ferric Sulfate Hydrate under Microwave Irradiation |
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| CHEN Xiao-yuan,YANG Yong,ZHANG Ai-hua.Synthesis of Cydohexyl Acetate Catalyzed by Ferric Sulfate Hydrate under Microwave Irradiation[J].Journal of Jishou University(Natural Science Edition),2008,29(4):71-74. |
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| Authors: | CHEN Xiao-yuan YANG Yong ZHANG Ai-hua |
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| Affiliation: | (College of Chemistry and Chemical Engineering,Jishou University,Jishou 416000，Hunan China) |
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| Abstract: | Cyclohexyl acetate was synthesized by using ferric sulfate hydrate as catalyst under microwave irradiation.The optimum experimental condition was obtained as follows:the power of microwave irradiation was 640 W,molar ratio of alcohol to acid was 1.4∶1,the dosage of water-carring reagent was 6 mL,the amount of catalyst was 1.0 g,and the reaction time was 30 min.Under the optimum experimental condition,the yield of the product was 91.6% (based on acetic acid). |
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| Keywords: | microwave irradiation ferric sulfate hydrate cyclohexyl acetate |
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