| 液化气加氢反应动力学研究 |
| |
| 引用本文： | 方向晨,艾抚宾,乔凯,祁文博,徐彤.液化气加氢反应动力学研究[J].石油化工,2013,42(4):399-403. |
| |
| 作者姓名： | 方向晨 艾抚宾 乔凯 祁文博 徐彤 |
| |
| 作者单位： | 中国石化抚顺石油化工研究院,辽宁抚顺,113001 |
| |
| 摘 要： | 液化气加氢作乙烯原料是解决乙烯原料不足的有效方法之一。为进一步了解该催化反应的特点,控制和优化反应条件,为该技术的中试放大及工业生产装置的设计提供基础数据,在固定床反应器上,对液化气在LH-10A催化剂上加氢制备烷烃的反应规律进行了研究,建立了反应动力学方程式:x(C=)=x(C0)-1/(Ke+1)]exp-k1(1+1/Ke)t]+1/(Ke+1);并分析了反应条件的影响。实验结果表明,低碳烯烃加氢为一级反应,且为快速反应;在实验温度范围内,所建立的反应动力学方程的计算值与实验值的相对误差小于15%,该反应动力学方程式可作为工业装置设计的依据。
|
| 关 键 词： | 丙烯 丁烯 动力学 液化气 加氢 乙烯原料 |
Dynamics of Liquefied Petroleum Gas Hydrogenation |
| |
| Fang Xiangchen
,
Ai Fubin
,
Qiao Kai
,
Qi Wenbo
,
Xu Tong.Dynamics of Liquefied Petroleum Gas Hydrogenation[J].Petrochemical Technology,2013,42(4):399-403. |
| |
| Authors: | Fang Xiangchen Ai Fubin Qiao Kai Qi Wenbo Xu Tong |
| |
| Affiliation: | (SINOPEC Fushun Research Institute of Petroleum and Petrochemicals,Fushun Liaoning 100029,China) |
| |
| Abstract: | The hydrogenation of liquefied petroleum gas on LH-10A catalyst in a fixed bed reactor was studied to provide raw materials for the production of ethylene.The reaction kinetics equation was got:x(C=)=x(C0)-1/(Ke+1)]exp-k1(1+1/Ke)t]+1/(Ke+1).The effects of reaction conditions on the hydrogenation were investigated.The experimental results show that the hydrogenation of light olefins is fast first order reactions.The relative error between the calculated values and the experimental value is less than 15%.The kinetics equation can be used as basis for the industrial design. |
| |
| Keywords: | propylene butene hydrogenation dynamics liquefied petroleum gas raw materials for ethylene |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《石油化工》浏览原始摘要信息 |
|
点击此处可从《石油化工》下载全文 |
|
