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Bioleaching of soluble phosphorus from rock phosphate containing pyrite with DES-induced Acidithiobacillus ferrooxidans
Authors:Ru-an Chi  Xiao-hui Huang  Chun-qiao Xiao  Yuan-xin Wu and Wen-xue Zhang
Affiliation:1. Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan Institute of Technology, Wuhan 430073, China;2. Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430073, China; 3. Yunnan Phosphate Chemical (Group) Co., Ltd., Kunming 650600, China)
Abstract:The effects of Acidithiobacillus ferrooxidans (At. f) mutated with diethyl sulfate (DES) as a mutagen on the bioleaching of soluble phosphorus (P) from rock phosphate (RP) were investigated. The results show that the oxidative activity of At. f is greatly improved by 1.0% (volume fraction) of DES. Correspondingly, the highest leaching rate of soluble P is also obtained to be 14.9% by the At. f mutated, which is 85.8% higher than that of the adapted At. f without mutation. In addition, the SEM images are significantly performed that the corrosion of RP residue surfaces leached by 1.0% DES-induced At.f is much worse than that of leached by the adapted At. f. All the above indicate that the leaching efficiency of soluble P from RP with pyrite can be greatly improved by using DES-induced At. f to a certain extent.
Keywords:bioleaehing  rock phosphate (RP)  Acidithiobacillusferrooxidans (At  f)  diethyl sulfate  soluble phosphorus  mutation
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