Chemistry of multifunctional polymers based on bis-MPA and their cutting-edge applications |
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| Affiliation: | 1. Department of Fibre and Polymer Technology, KTH Royal Institute of Technology, School of Chemical Science and Engineering, Stockholm, Sweden;2. Institute of Environmental Medicine, Nanosafety & Nanomedicine Laboratory, Karolinska Institutet, Stockholm, Sweden;1. Université de Lorraine, Laboratoire de Chimie Physique Macromoléculaire LCPM, UMR 7375, Nancy F-54000, France;2. CNRS, Laboratoire de Chimie Physique Macromoléculaire LCPM, UMR 7375, Nancy F-54000, France;3. Laboratoire de Chimie Organométallique et Macromoléculaire – Matériaux Composites, Université Cadi Ayyad, Faculté des Sciences et Techniques, Gueliz, Av. A. Khattabi, BP 549, 40000 Marrakech, Morocco;1. Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, PR China;2. Qingdao University of Science and Technology, Qingdao 266042, PR China;1. Université de Lorraine, Laboratoire de Chimie Physique Macromoléculaire LCPM, UMR 7375, Nancy F-54000, France;2. CNRS, Laboratoire de Chimie Physique Macromoléculaire LCPM, UMR 7375, Nancy F-54000, France;1. Departamento de Química Orgánica, Instituto de Ciencia de Materiales de Aragón (ICMA), Universidad de Zaragoza–CSIC, c/ Pedro Cerbuna 12, 50009 Zaragoza, Spain;2. INM – Leibniz Institute for New Materials, Campus D2 2, 66123 Saarbrücken, Germany;3. Centro Universitario de la Defensa, Academia General Militar, Ctra. de Huesca s/n, 50090 Zaragoza, Spain;4. Chemistry Department, Saarland University, 66123 Saarbrücken, Germany |
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| Abstract: | Polymers play an important role in the advancement of materials for use in cutting-edge applications. A direct consequence of an increased demand for more sophisticated materials has been a drive toward developing polymers that exhibit a higher level of structural control, especially in terms of the number and type of functionalities provided within the polymer framework. A family of polymers that meets such a challenge is based on the readily available AB2 monomer 2,2-bismethylolpropionic acid (bis-MPA) building block. Due to the ease with which the monomers can be synthesized, an array of multifunctional polymers have been produced including monodisperse dendrimers and dendrons and well-defined linear polymers as well as linear-dendritic hybridizations. This review outlines the evolution of the synthetic strategies for developing novel polymeric architectures based on bis-MPA and their assessment in both solution and substrate-based innovative applications. |
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| Keywords: | Bis-MPA Aliphatic polyester Dendritic polymers Polycarbonate Nanomaterials Biomedical applications |
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