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Increasing silver leaching rate from leaching-resistant zinc residues by thiourea leaching method with pressurized preoxidation process
作者姓名:胡天觉  曾光明  黄国和  袁兴中  李建兵
作者单位:Department of Environmental Science and Engineering,Hunan University,Changsha 410082,China,Department of Environmental Science and Engineering,Hunan University,Changsha 410082,China,Department of Environmental Science and Engineering,Hunan University,Changsha 410082,China,Department of Environmental Science and Engineering,Hunan University,Changsha 410082,China,Department of Environmental Science and Engineering,Hunan University,Changsha 410082,China
基金项目:Project( 2 0 0 1AA6 40 40 2)supportedbytheNationalAdvancedTechnologiesResearchFoundationofChina,Project( 70 1710 5 5 ,5 0 1790 11)supportedbytheNationalNaturalScienceFoundationofChina
摘    要:1 INTRODUCTIONAtpresent ,zincisproducedbythehydrometallurgy electroanalysismethodinmostzincsmeltingplants .Eachyear,millionstonsofhydrometallurgicalzincresiduesaredischargedfromChinesesmeltingplants ,whicharehighlyacidicandconsistofgreatdealofsilverandot…


Increasing silver leaching rate from leaching-resistant zinc residues by thiourea leaching method with pressurized preoxidation process
HU Tian-jue,ZENG Guang-ming,HUANG Guo-he,YUAN Xing-zhong,LI Jian-bing.Increasing silver leaching rate from leaching-resistant zinc residues by thiourea leaching method with pressurized preoxidation process[J].Transactions of Nonferrous Metals Society of China,2003,13(1).
Authors:HU Tian-jue  ZENG Guang-ming  HUANG Guo-he  YUAN Xing-zhong  LI Jian-bing
Abstract:As for the leaching-resistant zinc residues, the silver leaching rate can be over 98% through the processof pressurized preoxidation and thiourea leaching. Compared with the method of extracting the silver directly fromthe leaching-resistant zinc residues, the silver leaching rate is greatly improved. The optimum preoxidation condi-tions are: particle size range 40 - 60 μm, oxygen partial pressure 106 Pa, temperature 80 - 90 ℃, pH= 1.0, andleaching time 5 h. After pretreatment, the time of thiourea leaching silver is shortened to 1.5 h, and the thioureaconsumption is reduced greatly. The oxidation mechanism and the thiourea leaching kinetics were also explored.
Keywords:zinc residue  pressurized preoxidation  thiourea leaching  shrinking core model
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