| 疏水/亲水性大孔聚二乙烯基苯/聚丙烯酰乙二胺互贯树脂的合成及其孔结构研究 |
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| 引用本文： | 高淑芹,廖文文,谢祥林,徐满才.疏水/亲水性大孔聚二乙烯基苯/聚丙烯酰乙二胺互贯树脂的合成及其孔结构研究[J].湖南城市学院学报(自然科学版),2008,17(1):43-45. |
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| 作者姓名： | 高淑芹 廖文文 谢祥林 徐满才 |
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| 作者单位： | 湖南师范大学化学化工学院,长沙410081 |
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| 基金项目： | 国家自然科学基金资助项目(20474015);;湖南省教育厅科研基金资助项目(04A029) |
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| 摘 要： | 采用分步悬浮聚合法制备的大孔聚二乙烯基苯／聚丙烯酸甲酯互穿聚合物网络（Interpenetrating polymer networks IPN），经过乙二胺氨解，得到新型疏水／亲水性聚二乙烯基苯／聚丙烯酰乙二胺互穿网络（polydivinylbenzene／poly acrylethylenediamine IPN即PDVB／PAEMIPN）．孔结构研究表明，树脂的平均孔径达8．6～136nm．研究了混合致孔剂中良致孔剂与非良致孔剂的比例、两网质量比以及第二网交联度对树脂孔结构的影响．
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| 关 键 词： | 疏水／亲水 致孔剂 大孔树脂 互穿聚合物网络（IPN） |
Study on the Preparation and Pore Structure of a Hydrophobic/Hydrophilic Macroporous Polydivinylbenzene/Polyacrylethylenediamine IPN Resin |
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| GAO Shu-qin,LIAO Wen-wen,XIE Xiang-lin,XU Man-cai.Study on the Preparation and Pore Structure of a Hydrophobic/Hydrophilic Macroporous Polydivinylbenzene/Polyacrylethylenediamine IPN Resin[J].Journal of Hunan City University:Natural Science,2008,17(1):43-45. |
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| Authors: | GAO Shu-qin LIAO Wen-wen XIE Xiang-lin XU Man-cai |
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| Affiliation: | College of Chemistry and Chemical Engineering;Hunan Normal University;Changsha 410081;China |
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| Abstract: | A novel hydrophobic/hydrophilic macroporous crosslinked polydivinylbenzene/ polyacrylethylenediamine interpenetrating polymer network(PS/PAEM IPN)resin was prepared by using synthetic polystyrene/ polymethylacrylate(PS/PMA) IPN as material.Pore structure parameters of the target product were determined.The study of pore structure shows that average pore diameter is 8.6-13.6 nm.The effect of porogen,mass ratio of the two networks and crosslinking degree of the second networks on the pore structure of the PDV... |
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