Photolytic generation of an o-quinodimethane derivative and its reactions with unsaturated polymers |
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| Authors: | G Kevin Jordan Michael F Farona |
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| Affiliation: | (1) Department of Chemistry, University of North Carolina at Greensboro, Greensboro, NC 27412, USA, US |
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| Abstract: | Polybutadiene was treated with o-tolualdehyde under UV irradiation to produce random copolymers through Diels-Alder reactions on the backbone double bonds.
The physical properties of the polymer products change as more of the aldehyde attaches to it. The copolymers were characterized
by NMR spectroscopy. A bifunctional o-tolualdehyde was synthesized and used as a crosslinking agent.
Received: 19 September 1997/Accepted: 24 November 1997 |
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