| 氢化燃烧合成镁基储氢合金的电化学性能的研究 |
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| 引用本文： | 王以存,顾昊,蔡浩,陈忠元,朱云峰,李李泉.氢化燃烧合成镁基储氢合金的电化学性能的研究[J].功能材料,2007,38(A04):1637-1639. |
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| 作者姓名： | 王以存 顾昊 蔡浩 陈忠元 朱云峰 李李泉 |
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| 作者单位： | 南京工业大学材料科学与工程学院,江苏南京210009 |
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| 摘 要： | 研究了氢化燃烧合成Mg2NiH4产物的电化学性能，并探索了机械球磨处理对产物电化学性能的影响。电化学测试表明，HCS产物不经任何处理，最大放电容量仅为45.13mAh／g；产物球磨后最大放电容量和高倍率放电能力得到提高，如产物经球磨1h后，最大放电容量增至259．24mAh／g，产物添加3％（质量分数）的石墨球磨5h，最大放电容量增加了10倍以上，达到481．50mAh/g。
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| 关 键 词： | 镁基储氢合金 氢化燃烧合成 电化学性能 机械球磨 |
| 文章编号： | 1001-9731（2007）增刊-1637-03 |
| 修稿时间： | 2007-04-20 |
Electrochemical properties of magnesium based hydrogen storage alloys prepared by hydriding combustion synthesis |
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| WANG Yi-cun, GU Hao, CAI Hao, CHEN Zhong-yuan, ZHU Yun-feng, LI Li-quan.Electrochemical properties of magnesium based hydrogen storage alloys prepared by hydriding combustion synthesis[J].Journal of Functional Materials,2007,38(A04):1637-1639. |
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| Authors: | WANG Yi-cun GU Hao CAI Hao CHEN Zhong-yuan ZHU Yun-feng LI Li-quan |
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| Affiliation: | College of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210009, China |
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| Abstract: | The electrochemical properties of Mg2NiH4 prepared by hydriding combustion synthesis were investigated. The effect of ball milling on the electrochemical properties of HCS product was also studied. Electrochemical measurements showed that both maximum discharge capacity and high rate discharge ability were improved of the HCS product after ball milling. The maximum discharge capacity of the HCS product with lh of ball milling increased from 45.13 to 259.24mAh/g. A capacity of 481.50mAh/g was obtained for the HCS product ball-milled with 3wt.% graphite for 5h, which was ten times higher than the untreated one. |
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| Keywords: | magnesium based hydrogen storage alloys hydriding combustion synthesis electrochemical characteristics bali milling |
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