A novel lamellar coordination polymer incorporating partially overlapped helices,ladders and zigzag chains – Synthesis,crystal structure and magnetic property |
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| Affiliation: | 1. Polymer and Composite Division, Key Laboratory of Marine Materials and Related Techologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China;2. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China;3. Center for Membrane and Water Science & Technology, Zhejiang University of Technology, Hangzhou 310014, China;1. Department of Chemistry, University of Otago, P.O. Box 56, Dunedin 9054, New Zealand;2. The MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, P.O. Box 56, Dunedin 9054, New Zealand;3. Department of Oral Rehabilitation, Faculty of Dentistry, University of Otago, Dunedin 9054, New Zealand;1. Department of Chemistry and Science Institute, University of Iceland, 107 Reykjavík, Iceland;2. Department of Physics, Sophia University, Tokyo 102-8554, Japan;3. ARC Centre for Antimatter-Matter Studies, School of Chemical and Physical Sciences, Flinders University, Adelaide, SA 5001, Australia;4. Institute of Mathematical Sciences, University of Malaya, Kuala Lumpur 5063, Malaysia;5. Laboratório de Colisões Atómicas e Moleculares, CEFITEC, Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal |
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| Abstract: | The hydrothermal assembly of CoCl2 · H2O with benzene-1, 2, 3, 4-tetracarboxylic acid (H4mpda) yielded a novel lamellar coordination polymeric complex, Co2mpda(H2O)6 · H2O (1), in which each layer presents an interesting multifold topology: both as partially overlapped helices with alternate chirality and as alternately arranged ladders and zigzag chains. |
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