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Nanodiamond particles/reduced graphene oxide composites as efficient supercapacitor electrodes
Affiliation:1. Institut de Recherche Interdisciplinaire (IRI, USR 3078), Université Lille 1, Parc de la Haute Borne, 50 Avenue de Halley, BP 70478, 59658 Villeneuve d’Ascq, France;2. Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Shandong University, Jinan 250061, China;3. Aix Marseille University, CNRS, LP3 UMR 7341, 13288 Marseille, France;4. ALISTORE-ERI, CNRS, FR3104, France;5. Physical and Materials Chemistry Division, National Chemical Laboratory (CSIR-NCL), Pune 411 008, India;1. Department of Chemistry, Inha University, 100 Inharo, Incheon 22212, South Korea;2. Department of Mechanical Engineering, College of Engineering, Kyung Hee University, Yongin 17104, South Korea;1. Department of Chemistry, University of Mohaghegh Ardabili, Ardabil, Iran;2. Department of Biology, University of Mohaghegh Ardabili, Ardabil, Iran;3. Unité de Glycobiologie Structurale et Fonctionnelle (UGSF), Univ. Lille, CNRS, UMR 8576, 59655 Villeneuve d′Ascq, France;4. Univ. Lille, CNRS, Centrale Lille, ISEN, Univ. Valenciennes, UMR 8520-IEMN, F-59000 Lille, France;5. Biosensors and Bioelectronics Research Center (BBRC), Ardabil University of Medical Sciences, Ardabil, Iran;1. INM – Leibniz Institute for New Materials, Campus D2 2, 66123 Saarbrücken, Germany;2. Saarland University, Campus D2 2, 66123 Saarbrücken, Germany;1. Faculté des Sciences, Université Mouloud Mammeri, Tizi-Ouzou, Algeria;2. Centre de Recherche en Technologie des Semi-conducteurs pour l’Energétique (CRTSE), 2, Bd. Frantz Fanon, B.P. 140 Alger-7 merveilles, Algiers, Algeria;3. Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Shandong University, Jinan 250061, China;4. Institut d’Electronique, de Microélectronique et de Nanotechnologie (IEMN, CNRS-8520), Université Lille1, Avenue Poincaré – B.P. 60069, 59652 Villeneuve d’Ascq, France;1. Ilie Murgulescu Institute of Physical Chemistry, Splaiul Independentei 202, 060021 Bucharest, Romania;2. Univ. Lille, CNRS, Central Lille, ISEN, Univ. Valenciennes, UMR 8520, IEMN, F-59000 Lille, France;3. Département de Physique, Faculté des Sciences de Tunis, Université Tunis-El Manar, 2092, Tunisia;4. Laboratoire de Chimie Appliquée et Génie Chimique de l’Université Mouloud Mammeri de Tizi-Ouzou, Algeria;5. National R&D Institute for Chemistry and Petrochemistry – ICECHIM, Splaiul Independentei 202, 060021 Bucharest, Romania;1. Univ. Lille, CNRS, Centrale Lille, ISEN, Univ. Valenciennes, UMR 8520 – IEMN, F-59000 Lille, France;2. Univ. Lille, CNRS, UMR 8207 – UMET, F-59000 Lille, France;3. Université de Bordeaux, ICMCB, 87 Av. Doc. A. Schweitzer, F-33608 Pessac, France
Abstract:The paper reports on the preparation of reduced graphene oxide (rGO) modified with nanodiamond particles composites by a simple solution phase and their use as efficient electrode in electrochemical supercapacitors. The technique relies on heating aqueous solutions of graphene oxide (GO) and nanodiamond particles (NDs) at different ratios at 100 °C for 48 h. The morphological properties, chemical composition and electrochemical behavior of the resulting rGO/NDs nanocomposites were investigated using UV/vis spectrometry, Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, transmission electron microscopy (TEM) and electrochemical means. The electrochemical performance, including the capacitive behavior of the rGO/NDs composites were investigated by cyclic voltammetry and galvanostatic charge/discharge curves at 1 and 2 A g?1 in 1 M H2SO4. The rGO/ND matrix with 10/1 ratio displayed the best performance with a specific capacitance of 186 ± 10 F g?1 and excellent cycling stability.
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