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一种新型无磷缓蚀阻垢剂的实验研究
引用本文:曾德芳,胡丹,张伟,张水生,丁复军.一种新型无磷缓蚀阻垢剂的实验研究[J].云南化工,2011(5):1-6.
作者姓名:曾德芳  胡丹  张伟  张水生  丁复军
作者单位:武汉理工大学资源与环境工程学院湖北省矿物资源加工与环境重点实验室;湖北诗璐化工涂料有限公司;
基金项目:国家2010年中小企业技术创新基金(基金号:10C26214202268)
摘    要:以水解聚马来酸酐(HPMA)、聚环氧琥珀酸(PESA)、葡萄糖酸钠、D-异抗坏血酸钠和锌盐为原料,研制出一种新型无磷缓蚀阻垢剂。利用旋转挂片腐蚀实验、静态阻垢实验和电化学实验研究了该无磷缓蚀阻垢剂的缓蚀和阻垢性能。结果表明,无磷缓蚀阻垢剂的质量浓度为50 mg/L时,缓蚀率和阻垢率分别达到90%和98%以上;该无磷缓蚀阻垢剂是一种以抑制阳极为主的混合型缓蚀阻垢剂,在A3碳钢表面的吸附遵循Langmuir吸附等温方程。

关 键 词:无磷缓蚀阻垢剂  缓蚀性能  阻垢性能

Experimental Study on a Novel Phosphorus-free Corrosion and scale Inhibitor
ZENG De-fang,HU Dan,ZHANG Wei,ZHANG Shui-sheng,DING Fu-jun.Experimental Study on a Novel Phosphorus-free Corrosion and scale Inhibitor[J].Yunnan Chemical Technology,2011(5):1-6.
Authors:ZENG De-fang  HU Dan  ZHANG Wei  ZHANG Shui-sheng  DING Fu-jun
Affiliation:ZENG De-fang1,HU Dan1,ZHANG Wei1,ZHANG Shui-sheng2,DING Fu-jun2(1.School of Resource and Environmental Engineering,Wuhan University of Technology,Hubei Key Lab of Mineral Resource Processing and Environment,Wuhan,430070,.China,2.Hubei Shilu Chemical Coat Company,Yingcheng 432407,China)
Abstract:A novel phosphate-free corrosion and scale inhibitor was obtained from hydrolytic polymaleic anhydride,polyepoxysuccinic acid,sodium gluconate,Sodium and Zinc D-erythorbates.The performance of corrosion and scale inhibition were evaluated by rotary hanging-piece corrosion test,scale inhibition test and electrochemical experiment.The results showed that the dosage of the phosphate-free corrosion and scale inhibitor was 50 mg·L-1,the maximum inhibition and scale inhibition exceeded 90% and 98%,respectively.The phosphate-free corrosion and scale inhibitor mainly inhibits the anode process of corrosion and belongs to mixed-type corrosion and scale inhibitor.And the adsorption of the phosphate-free corrosion and scale inhibitor on A3 metal surface obeys Langmuir adsorption isotherm equation.
Keywords:phosphate-free corrosion and scale inhibitor  corrosion performance  scale inhibition  
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