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Characterization of hydrotreated Cu-ZSM-5 catalyst for the selective catalytic reduction of NO by n-decane
Authors:Hassib Tounsi  Samir Djemel  Abdelhamid Ghorbel  Gérard Delahay  Louis Charles de Menorval and Bernard Coq
Affiliation:(1) Laboratoire de Chimie des Matériaux et Catalyse, Département de Chimie, Faculté des Sciences de Tunis Campus Universitaires, 1060 Tunis, Tunisie;(2) Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR 5618 CNRS ENSCM, 8 rue de l'Ecole Normale, 34053 Montpellier Cedex, France
Abstract:The steam treatment of Cu-ZSM-5 prepared by solid ion exchange involves an important decrease of the NO conversion. Characterization of the solids by NO-TPD, H2-TPR, 27Al MAS NMR shows that the catalyst deactivation is mainly due to change in copper species rather than the collapse of the zeolite framework.This revised version was published online in December 2005 with corrections to the Cover Date.
Keywords:NO-SCR-C10H22  catalyst deactivation  hydrothermal treatment  Cu-ZSM-5
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