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Kinetics of reactions involved in pyrolysis of cellulose I. The three reaction model
Authors:Ravindra K Agrawal
Abstract:Kinetics of reactions involved in pyrolysis of cellulose has been modeled in terms of a three reaction model. In this model it is assumed that cellulose decomposes to tars, chars and gaseous products via three competitive first-order reactions. Arrhenius parameters have been obtained to describe the rate constants of these reactions. The three reaction model predicts the weight loss data reasonably well. Product yields of tars, chars and gases predicted by the three reaction model are compared over the temperature range 250 to 360°C. In this communication a technique for analyzing experimental data of a solid state reaction is presented.
Keywords:cellulose pyrolysis  biomass pyrolysis  kinetics of pyrolysis  pyrolysis model
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