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Synthesis of hybrid Pt/TiO2 (anatase)/MWCNTs nanomaterials by a combined sol–gel and polyol process
Authors:KN Lin  WJ Liou  TY Yang  HM Lin  CK Lin  SH Chien  WC Chen  SH Wu
Affiliation:1. Department of Materials Engineering, Tatung University, Taipei 104, Taiwan;2. Institute of Physics, Academia Sinica, Nankang, Taipei 115, Taiwan;3. Department of Materials Science and Engineering, Feng Chia University, Taichung, Taiwan;4. Institute of Chemistry, Academia Sinica, Nankang, Taipei 115, Taiwan;5. Department of Chemical and Material Engineering, National Yunlin University of Science and Technology, Yunlin 640, Taiwan
Abstract:In the present study, hybrid Pt/TiO2/MWCNTs nanomaterials are prepared successfully by a combined sol–gel and polyol process. The as-prepared nanomaterials are characterized by X-ray diffraction, high resolution transmission electron microscopy, and thermogravimetry analysis. In addition, its catalytic performance by converting CO into CO2 is also evaluated. Experimental results show that the hybrid Pt/TiO2/MWCNTs nanomaterials exhibit a mixture of anatase TiO2 and Pt phases. Multi-wall carbon nanotubes serve as an excellent supporting material where anatase TiO2 nanoparticles are decorated with well-distributed Pt nanoparticles. Excellent catalytic performance can be revealed for the hybrid Pt/TiO2/MWCNTs nanomaterials. When compared with its Pt/TiO2 counterparts where ~ 100% CO conversion occurred at 150 °C, almost 100% conversion of CO into CO2 can be observed at a temperature ranged from 30 °C to 100 °C.
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