| 新型含三嗪环希夫碱大环化合物的合成及其离子识别研究 |
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| 引用本文： | 赵军龙.新型含三嗪环希夫碱大环化合物的合成及其离子识别研究[J].精细化工,2014,31(8). |
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| 作者姓名： | 赵军龙 |
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| 作者单位： | 西北大学化学与材料科学学院 |
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| 摘 要： | 以三聚氯氰、二乙胺、对硝基酚、1,2-二溴乙烷、水杨醛、对羟基苯甲醛、香草醛和异香草醛为原料，采用高度稀释法合成了一类新型的含三嗪环的席夫碱大环化合物，并通过IR、1H NMR和ESI/MS对其结构进行了表征。紫外光谱研究表明，席夫碱大环5对Fe3+离子有专一性识别作用。
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| 关 键 词： | 离子识别、大环、希夫碱、合成、三嗪环 |
| 收稿时间： | 4/8/2014 12:00:00 AM |
| 修稿时间： | 2014/5/14 0:00:00 |
Synthesis and Ion Recognition of Novel Schiff Base Macrocyclic Compounds Containing Thiotriazinone |
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| ZHAO Jun-long.Synthesis and Ion Recognition of Novel Schiff Base Macrocyclic Compounds Containing Thiotriazinone[J].Fine Chemicals,2014,31(8). |
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| Authors: | ZHAO Jun-long |
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| Abstract: | Several novel Schiff base macrocyclic compounds of Thiotriazinone were synthesized from cyanuric chloride, diethylamine p-nitrophenol, 1,2-dibromoethane, salicylaldehyde, p-hydroxybenzaldehyde, vanillin and isovanillin by high dilution method, and their structures were characterized by IR, 1H NMR and ESI/MS techniques. The studies on the UV-Vis absorption spectroscopies show that Schiff base 5 have a selective recognition for Fe3+. |
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| Keywords: | ion recognition macrocyclic compound Schiff base synthesis thiotriazinone |
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