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强化UV/Fenton法降解水中苯酚的研究
引用本文:张乃东,黄君礼,郑威.强化UV/Fenton法降解水中苯酚的研究[J].环境工程学报,2002,3(2):20-22.
作者姓名:张乃东  黄君礼  郑威
作者单位:1. 哈尔滨工业大学市政与环境工程学院,哈尔滨,150090;黑龙江大学化学化工学院,哈尔滨,150080
2. 哈尔滨工业大学市政与环境工程学院,哈尔滨,150090
3. 哈尔滨理工大学材料学院,哈尔滨,150040
摘    要:研究了UV/Fenton法处理含苯酚废水时H2 O2 和FeSO4 加入量及苯酚初始浓度对酚去除效果的影响及C2 O2 -4 对UV/Fenton法的增强效果。 H2 O2 ]=2 0mmol/L ,FeSO4 ]=5mmol/L ,反应 2 0min ,苯酚初始浓度为 5 0mg/L时 ,酚去除率达 99%。UV/Fenton体系中引入C2 O2 -4 后可有效提高对紫外和可见光的利用率 ,进而提高了对高浓度苯酚废水去除效果

关 键 词:过氧化氢  羟自由基·OH  光降解  草酸铁络合物  苯酚

Treatment of phenols-containing wastewater by photo-Fenton process
Zhang Naidong , Huang Junli Zheng Wei.Treatment of phenols-containing wastewater by photo-Fenton process[J].Techniques and Equipment for Environmental Pollution Control,2002,3(2):20-22.
Authors:Zhang Naidong  Huang Junli Zheng Wei
Affiliation:Zhang Naidong 1,2 Huang Junli 1 Zheng Wei 3
Abstract:The UV/Fenton process is an advanced oxidation process, by which phenols in wastewater can be degraded. Here we investigated the effect of the adding amount of FeSO 4 ?H 2O 2 and the initial concentration of phenols in wastewater on the removal efficiency of phenols. When the concentration of H 2O 2 and FeSO 4 added are 20 and 5mmol/L in water sample, respectively, the phenols removing efficiency is up to 99% after reacting for 20min with the initial concentration, 50mmol/L. The utilizing rate of ultraviolet and visible light would be promoted by adding C 2O 2- 4 ions into UV/Fenton system, therefore the phenols removal efficiency can be increased.
Keywords:hydrogen peroxide  hydroxyl radical  photo degradation  ferrioxalate complexes  phenol
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