| 胶束增敏水相光度法测定铼（Ⅶ）的研究 |
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| 引用本文： | 滕洪辉,周晓光,邓桂春.胶束增敏水相光度法测定铼（Ⅶ）的研究[J].松辽学刊,2007,28(4):52-54. |
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| 作者姓名： | 滕洪辉 周晓光 邓桂春 |
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| 作者单位： | 滕洪辉（吉林师范大学,环境工程学院,吉林,四平,136000）;周晓光（吉林师范大学,环境工程学院,吉林,四平,136000）;邓桂春（辽宁大学,化学科学与工程学院,辽宁,沈阳,110036） |
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| 摘 要： | 研究了ReO4ˉ与碱性染料形成的离子缔合物不用苯等有机溶剂萃取，通过加入表面活性剂形成ReO4ˉ-乙基紫-聚乙烯醇三元胶束增溶增敏体系，在水相直接显色测定的新方法．该方法的线性范围为0-10μg／10mL，回归方程为A=0．0729 CμG/10mL-0．0001，相关系数r=0．9994，摩尔吸光系数ελ=647=1．36×10^5L·mol^-1·cm^-1，检测限为1．4×10^-3／μg／mL．用于烟道灰等样品中痕量铼的测定，RSD为3．25—3．34％，加标回收率为99．1—100．6％．
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| 关 键 词： | 铼(Ⅶ) 胶束 水相光度法 |
| 文章编号： | 1000-1840-（2007）04-0052-03 |
| 收稿时间： | 2007-09-17 |
| 修稿时间： | 2007年9月17日 |
Research of Micelle-Sensitized-Photometric Determination of Rhenium(Ⅶ) on the Water Phase |
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| TENG Hong-hui,ZHOU Xiao-guang,DENG Gui-chun.Research of Micelle-Sensitized-Photometric Determination of Rhenium(Ⅶ) on the Water Phase[J].Songliao Journal (Natural Science Edition),2007,28(4):52-54. |
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| Authors: | TENG Hong-hui ZHOU Xiao-guang DENG Gui-chun |
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| Affiliation: | TENG Hong - hui, ZHOU Xiao - guang, DENG Gui - chun ( 1. College of Environmental Engineering, Jilin Normal University, Siping 136000, China; 2. College of Chemical Science and Engineering, Liaoning University, Shenyang 110036, China) |
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| Abstract: | In the presence of polyethyl alcohol, the coloring reaction conditions of ReO4ˉ - Ethyl violet - Polyethyl alcohol have been studied, a novel ,way to directly determine Rhenium（Ⅶ ） have been established. The lincar range of the determination is 0. 0 - 10.0μg/10mL. Regression equation is A = 0. 0729Cμg/10.0mL - 0.0001. A molar absorptivity of it is 1.36 × 105 L/mol^-1 cm^-1. Limit of detection is 1.4 × 10^-3μg/mL. In the presence of fight quantity citric acid or tartaric add, molybdenum and tungsten do not interfere detection. The way is used to determine trace rbenium in flue dust, molybdenum trioxide and molybdenum mine. The recovery is 97.0- 100.6%. We can also obtain a satisfactory result. |
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| Keywords: | rhenium（ Ⅶ ） micellte photometric |
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