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Polypyrrole/reduced graphene oxide coated fabric electrodes for supercapacitor application
Affiliation:1. Institute for Superconducting and Electronic Materials, University of Wollongong, Australia;2. ARC Centre of Excellence for Electromaterials Science, University of Wollongong, Australia;1. Departamento de Ingeniería Textil y Papelera, EPS de Alcoy, Universitat Politècnica de València, Plaza Ferrándiz y Carbonell s/n, 03801 Alcoy, Spain;2. 2C2T – Centro de Ciência e Tecnologia Têxtil, Universidade do Minho, Campus de Azurém, 4800-058 Guimarães, Portugal;1. Nanomaterials and System Lab, Faculty of Applied Energy System, Science and Engineering College, Jeju National University, Jeju 690-756, Republic of Korea;2. Nanomaterials and System Lab, Department of Mechatronics Engineering, Engineering College, Jeju National University, Jeju 690-756, Republic of Korea;3. School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332-0245, USA
Abstract:Flexible and wearable energy storage devices are strongly demanded to power smart textiles. Herein, reduced graphene oxide (RGO) and polypyrrole (PPy) were deposited on cotton fabric via thermal reduction of GO and chemical polymerization of pyrrole to prepare textile-based electrodes for supercapacitor application. The obtained PPy–RGO-fabric retained good flexibility of textile and was highly conductive, with the conductivity of 1.2 S cm?1. The PPy–RGO-fabric supercapacitor showed a specific capacitance of 336 F g?1 and an energy density of 21.1 Wh kg?1 at a current density of 0.6 mA cm?2. The RGO sheets served as conductor and framework under the PPy layer, which could facilitate electron transfer between RGO and PPy and restrict the swelling and shrinking of PPy, thus resulting in improved electrochemical properties respect to the PPy-fabric device.
Keywords:Polypyrrole  Reduced graphene oxide  Fabric electrode  Supercapacitor
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