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硫酸锌生产除铁工艺及其比较
引用本文:刘俊峰,易平贵,陈安国.硫酸锌生产除铁工艺及其比较[J].无机盐工业,2001,33(1):35-36.
作者姓名:刘俊峰  易平贵  陈安国
作者单位:湘潭工学院化学工程系,
摘    要:研究了硫酸锌生产中用氧气或空气氧化法配合过氧化氢深度氧化除铁,其适宜的工艺条件为:氧气或空气氧化,pH值4-5,反应温度85-95℃,氧化时间2-3h,过氧化氢氧化,pH值3-4,反应温度80-85℃,氧化时间3-4h,过氧化氢的量控制为2-3g/L ,溶液中铁含量可控制在0.01g/L以下,同时与其他除铁工艺进行了比较,得出本艺具有操作条件容易控制,除铁效果较好等优点。

关 键 词:硫酸锌  氧气  过氧化氢  除铁  工艺
文章编号:1006-4990(2001)01-0035-02
修稿时间:2000年8月1日

TECHNOLOGIES AND COMPARISON OF IRON REMOVAL IN THE PRODUCTION OF ZINC SULFATE
LIU Junfeng et al..TECHNOLOGIES AND COMPARISON OF IRON REMOVAL IN THE PRODUCTION OF ZINC SULFATE[J].Inorganic Chemicals Industry,2001,33(1):35-36.
Authors:LIU Junfeng
Abstract:The technology of iron removal in the production of zinc sulfate by oxygen oxidizing following with deep oxidization of H2O2 has been studied. The suitable conditions are as following:with oxygen oxidizing, pH4~5,temperature 85~90℃,reaction time 2~3h; with oxidization of H2O2, pH3~4, temperature 80~85℃, reaction time 3~4h, the dosage of H2O2~3g/L.Under the above conditions,the content of ferric ions in acidic leaching liquid can be decreased below 0.01 g/L. Comparing with other method,this method has the advantages of easy conytrol and better effectiveness of iron removal
Keywords:zinc sulfate  oxygen  hydrogen peroxide  iron removal
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