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EG协同三嗪系大分子膨胀型阻燃剂阻燃HDPE研究
引用本文:黄庆敏,高帅,李斌,王玉峰.EG协同三嗪系大分子膨胀型阻燃剂阻燃HDPE研究[J].化学与粘合,2014(3):191-193.
作者姓名:黄庆敏  高帅  李斌  王玉峰
作者单位:东北林业大学,黑龙江省阻燃材料分子设计与制备重点实验室,黑龙江 哈尔滨150040
摘    要:研究了EG协同三嗪系大分子膨胀型阻燃剂阻燃HDPE,通过极限氧指数(LOI)、热重分析(TGA)、扫描电镜(SEM)等测试手段进行了分析。结果表明当EG与APP/CFA/SiO2共同使用阻燃HDPE的氧指数比单独加入两种阻燃剂的氧指数都有所提高,SEM测试表明EG与APP/CFA/SiO2共同使用燃烧后表面形成一层致密的保护层,阻止了聚合物的进一步燃烧。

关 键 词:高密度聚乙烯  膨胀阻燃  可膨胀石墨

Study on the Flame Retarding of HDPE by Synergetic Flame Retardance between EG and Triazine Macromolecular Intumescent Flame Retardant
HUANG Qing-min,GAO Shuai,LI Bin,WANG Yu-feng.Study on the Flame Retarding of HDPE by Synergetic Flame Retardance between EG and Triazine Macromolecular Intumescent Flame Retardant[J].Chemistry and Adhesion,2014(3):191-193.
Authors:HUANG Qing-min  GAO Shuai  LI Bin  WANG Yu-feng
Affiliation:(Key Lab of Molecular Design and Preparation of Flame Retarded Materials, Northeast Forestry University, Harbin 150040, China)
Abstract:The flame retarding of HDPE by synergetic flame retardance between EG and triazine macromolecular expansion flame retardant was studied. By means of the limiting oxygen index (LOI), thermal gravimetric analysis (TGA) and scanning electron microscope (SEM) tests, etc, the analysis was carried out. The research results showed that the LOI of flame-retardant HDPE with EG and APP/CFA/SiO2 was better than the LOI that the two kinds of flame retardants used alone. The SEM test indicated that there was a compact protective layer formed on the surface after combustion when EG and APP/CFA/SiO2 were used synergistically, which prevented further combustion of the polymer.
Keywords:HDPE  intumescent flame retardant  expandable graphite
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