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CPE增韧硬质聚氯乙烯的结构形态和增韧机理
引用本文:周丽玲,蔺玉胜,等.CPE增韧硬质聚氯乙烯的结构形态和增韧机理[J].中国塑料,2002,16(11):36-39.
作者姓名:周丽玲  蔺玉胜
作者单位:青岛科技大学高分子科学与工程学院 山东青岛266042 (周丽玲,蔺玉胜,杨静漪),青岛科技大学高分子科学与工程学院 山东青岛266042(吴其晔)
摘    要:对氯化聚乙烯(CPE)改性聚氯乙烯(PVC)体系的性能随组成的变化进行了研究。用电子显微镜(TEM、SEM)考察了共混体系的形态结构。结果发现:PVC和CPE相容性较好,共混体系在断裂过程中产生网丝结构。网丝结构与CPE用量密切相关,是脆-韧转变后体系发生塑性变形的结果,是PVC基体韧性突增的主要原因。

关 键 词:CPE  增韧  硬质聚氯乙烯  结构形态  增韧机理  形态分析

Morphology and Toughening Mechanism of Modified Rigid-PVC Systems
ZHOU Li-ling,LIN Yu-sheng,YANG Jing-yi,WU Qi-ye.Morphology and Toughening Mechanism of Modified Rigid-PVC Systems[J].China Plastics,2002,16(11):36-39.
Authors:ZHOU Li-ling  LIN Yu-sheng  YANG Jing-yi  WU Qi-ye
Abstract:Properties of PVC/CPE blends were studied. Morphological structures of these blends were investigated by TEM and SEM.It is showed that the compatibility of PVC and CPE was better. Filament occurred at the break surface, and filament was relative to the CPE contents. Emersion of filament resulted from the plastic deformation by brittle ductile transform of matrix and was also the main cause of PVC toughening.
Keywords:morphological analysis  poly(vinyl chloride)  chlorinated polyethylene  toughening modification
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