| 富勒烯的色谱分离模型 |
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| 引用本文： | 蒋元力,陈卫航,黄强,王福安.富勒烯的色谱分离模型[J].郑州大学学报(工学版),2003,24(2):48-52. |
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| 作者姓名： | 蒋元力 陈卫航 黄强 王福安 |
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| 作者单位： | 郑州大学化工学院,河南,郑州,450002 |
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| 基金项目： | SupportedbyHenanScientificFoundationofProfoundYouth(2000011) |
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| 摘 要： | 在分子热力学理论的基础上，建立了高效液相色谱中富勒烯的分离因子与柱温、碳数、流动相组成之间的定量相关模型，用不同来源的C70和C60-C96实验数据对该模型进行了检验，结果表明本模型具有广泛的适用性和相当令人满意的可靠性．
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| 关 键 词： | 富勒烯 色谱分离模型 分子热力学 分离因子 定量相关模型 |
The Chromatographic Separation Model for Fullerenes |
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| Abstract.The Chromatographic Separation Model for Fullerenes[J].Journal of Zhengzhou University: Eng Sci,2003,24(2):48-52. |
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| Authors: | Abstract |
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| Abstract: | Based on the molecular thermodynamic theory,the quantitative relationships between the separation factor and the column temperature,carbon number and mobile phase composition for fullerenes in high performance liquid chromatography are established.The corresponding models are testified by the experimental data of C70 and C60～C96 from different sources.The calculated results show good agreement with the experimental data. |
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| Keywords: | Fullerenes separation factor quantitative relationship molecular thermodynamics |
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