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叔丁基对苯二酚的合成研究
引用本文:蔡可迎,翟富民,魏贤勇.叔丁基对苯二酚的合成研究[J].精细石油化工进展,2000,1(11):4-6.
作者姓名:蔡可迎  翟富民  魏贤勇
作者单位:中国矿业大学化工学院,徐州,221008
摘    要:研究了以对苯二酚和叔丁醇为原料在固体酸催化下合成叔丁基对苯二酚,反应在极性溶剂与非极性溶剂的混和溶剂中进行,结果表明,叔丁基对苯二酚的选择性明显提高,收率为47.1%时选择性可达89.1%,具有工业化价值。

关 键 词:叔丁基对苯二酚  烷基化  合成  固体酸催化  选择性
修稿时间:2000-07-24

Synthesis of Tert-butylhydroquinone
Cai Keying,Zhai Fumin,Wei Xianyong.Synthesis of Tert-butylhydroquinone[J].Advances in Fine Petrochemicals,2000,1(11):4-6.
Authors:Cai Keying  Zhai Fumin  Wei Xianyong
Abstract:The titled compound was synthesized from hydroquinone and tert-butanol under catalysis of solid acid. The effects such as reaction time,reaction temperature, and solvents on the yield of tert-butylhydroquinone were also examined. In mixed organic solvents,the selectivity of tert-butylhydro-quinone was higher than that reported in the literature. Because of its high selectivity and mild condi-tions, this method is useful for preparing tert-butylhydroquinone and is promising in industrial applica-tion.
Keywords:tert-butylhydroquinone  alkylation  synthesis  solid acid catalysis  selectivity  
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