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激光剥蚀电感耦合等离子体质谱微区分析 进展评述
引用本文:王岚,杨理勤,王亚平,冯亮,陈雪,陈占生.激光剥蚀电感耦合等离子体质谱微区分析 进展评述[J].地质通报,2012,31(4):637-645.
作者姓名:王岚  杨理勤  王亚平  冯亮  陈雪  陈占生
作者单位:1. 武警黄金地质研究所,河北廊坊065000;中国地质大学(北京)地学实验中心,北京100083
2. 武警黄金地质研究所,河北廊坊,065000
3. 国家地质实验测试中心,北京,100037
基金项目:中国人民武装警察部队黄金指挥部博士后科研基金项目《激光剥蚀电感耦合等离子体的基础理论及地球化学应用研究》(编号:WH12-02);黄金专项《LA-ICP-MS和X射线荧光在地质勘查中的应用》(编号:HKY2012-04)
摘    要:激光剥蚀电感耦合(LA-ICP-MS)等离子体以其高空间分辨率、高灵敏度、多元素同时测定并可提供同位素比值信息的检测能力在原位微区分析中已得到广泛应用。现从仪器的发展、基础研究等方面评述了近年来LA-ICP-MS微区分析的进展,重点介绍了与等离子体质谱(ICP-MS)联用的激光器(纳秒和飞秒激光器)的发展、校正方法、分馏效应及其在地球科学微量元素、同位素、包裹体分析中的应用。并简要地阐述了LA-ICP-MS分析技术存在的局限和发展趋势。

关 键 词:激光剥蚀电感耦合等离子体(LA-ICP-MS)  微区分析  地球科学  评述

Developments of laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) in microanalysis
WANG Lan , YANG Li-qin , WANG Ya-ping , FENG Liang , CHEN Xue , CHEN Zhan-sheng.Developments of laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) in microanalysis[J].Geologcal Bulletin OF China,2012,31(4):637-645.
Authors:WANG Lan  YANG Li-qin  WANG Ya-ping  FENG Liang  CHEN Xue  CHEN Zhan-sheng
Affiliation:1. Geological Institute of Gold Armed Police Army, Langfang 065000, Hebei, China; 2. Geologic Labs Center, China University of Geosciences, Beijing 100083, China; 3. National Research Center for Geoanalysis, Beijing 100037, China
Abstract:Laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) has been widely used in microanalysis because of its high sensitivity, low detection limits, the determination of major, minor and trace elements in solids, as well as isotope-ratio measurements. This review aims to summarize recent developments in LA-ICP-MS based on the instrumental and fundamental aspects. Emphasis is placed on the developments of laser ablation for sample introduction to ICP-MS(nanosecond and femtosecond laser), calibration strategies, fraction effects and its applications of minor element, isotope and melt and fluid inclusions in geosciences. At the same time, the limitations and future developments of LA-ICP-MS microanalysis techniques are also discussed.
Keywords:laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS)  microanalysis  geoscience  review
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