| 镁基储氢材料用于噻吩加氢反应 |
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| 引用本文： | 周仕学,张鸣林,牛海丽,王盼盼,孔祥荣,吕德良.镁基储氢材料用于噻吩加氢反应[J].功能材料,2011,42(3):537-539. |
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| 作者姓名： | 周仕学 张鸣林 牛海丽 王盼盼 孔祥荣 吕德良 |
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| 作者单位： | 山东科技大学化学与环境工程学院; |
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| 基金项目： | 国家自然科学基金资助项目(50574054) |
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| 摘 要： | 用煤基碳作为助磨剂,将镁在氮气中进行反应球磨制得储氮材料,然后利用储氮材料在一定温度下受热时释放出的氮使噻吩发生加氢反应生成H2S.结果表明,储氮材料在低于差示扫描童热分析仪测定的初始放氢温度下就能使噻吩加氮生成HZS,在适宜温度下储氮材料的放氮与噻吩的加氮相匹配时可生成较多的H2S;反应后储氮材料中的MgH2释放出氮...
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| 关 键 词： | 储氢材料 镁 噻吩 加氢反应 |
Hydrogenation reaction of thiophene by magnesium-based hydrogen-storage materials |
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| ZHOU Shi-xue,ZHANG Ming-lin,NIU Hai-li,WANG Pan-pan,KONG Xiang-rong,LV De-liang.Hydrogenation reaction of thiophene by magnesium-based hydrogen-storage materials[J].Journal of Functional Materials,2011,42(3):537-539. |
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| Authors: | ZHOU Shi-xue ZHANG Ming-lin NIU Hai-li WANG Pan-pan KONG Xiang-rong LV De-liang |
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| Affiliation: | ZHOU Shi-xue,ZHANG Ming-lin,NIU Hai-li,WANG Pan-pan,KONG Xiang-rong,LV De-liang(College of Chemical and Environmental Engineering,Shandong University of Science and Technology,Qingdao 266510,China) |
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| Abstract: | The hydrogen-storage materials were prepared from magnesium by reactive ball-milling under hydrogen atmosphere with coal-based carbon as milling aid,and then the hydrogen-storage materials were utilized for the hydrogenation reaction of thiophene to convert into H2S with the hydrogen released from the materials at certain temperatures.It was shown that hydrogenation reaction of thiophene took place at the temperature lower than the initial dehydrogenation temperature of the hydrogen-storage materials determ... |
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| Keywords: | hydrogen-storage material magnesium thiophene hydrogenation reaction |
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