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燃煤烟气中脱汞吸附剂的性能实验研究
引用本文:薛长海,李鑫,耿合先,于红广,程伟,张安超.燃煤烟气中脱汞吸附剂的性能实验研究[J].华中电力,2009,22(4):1-3.
作者姓名:薛长海  李鑫  耿合先  于红广  程伟  张安超
作者单位:1. 焦作电大,河南 焦作,454159
2. 新乡豫新发电有限公司,河南 新乡,453011
3. 华中科技大学煤燃烧国家实验室,湖北 武汉,430074
摘    要:利用制备的壳聚糖吸附剂在一维煤粉炉进行烟气除汞实验,实验发现:壳聚糖类吸附剂可以有效脱除燃煤烟气中的汞,最高效率可达到96%;并利用红外光谱分析了其微观结构,揭示了壳聚糖类吸附剂吸附螯舍痕量重金属汞汞机理为4个游离氨基螯合1个汞或2个游离氨基和2个羟基协同螯合一个汞。其中氨基是主要反应活性基。

关 键 词:  红外光谱  吸附

Experiment Research of Sorbents to Remove Mercury from Coal-Fired Flue Gas
XUE Chang-hai,LI Xin,GENG He-xian,YU Hong-guang,CHENG Wei,ZHANG An-chao.Experiment Research of Sorbents to Remove Mercury from Coal-Fired Flue Gas[J].Central China Electric Power,2009,22(4):1-3.
Authors:XUE Chang-hai  LI Xin  GENG He-xian  YU Hong-guang  CHENG Wei  ZHANG An-chao
Affiliation:1.Jiaozuo Power Plant;Jiaozuo 454159;China;2.Xinxiang YuXin Power Generation Co;LTD;Xinxiang 453011;China
Abstract:Aone-dimensionalfurnacetest bench experiment was conducted to study the Chitosan sorbent's adsorption efficiency of mercury in coal-fired flue gas.Three kinds of modified Chitosan(CTS)sorbents are prepared to remove the mercury in the flue gas.The CTS sorbents exhibit high mercury removal efficiency,as much as 96%.Fresh and after adsorption of the same kind of sorbents were compared by using Fourier transform infrared spectroscopy(FTIR).The results show that the mechanism of CTS removing mercury is that 4 f...
Keywords:mercury  FTIR  adsorption  
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