| 3-叠氮甲基-3-甲基氧丁环的合成 |
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| 引用本文： | 李娜,甘孝贤.3-叠氮甲基-3-甲基氧丁环的合成[J].火炸药学报,2005,28(3):57-59. |
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| 作者姓名： | 李娜 甘孝贤 |
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| 作者单位： | 西安近代化学研究所,陕西,西安,710065;西安近代化学研究所,陕西,西安,710065 |
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| 摘 要： | 以三羟甲基乙烷与碳酸二乙酯为原料,经环化反应合成了3-羟甲基-3-甲基氧丁环(HMM O)。在低温下,HMM O与对甲苯磺酰氯反应生成3-磺酸酯甲基-3-甲基氧丁环(M TM O)。M TM O和叠氮化钠发生叠氮化反应形成叠氮单体3-叠氮甲基-3-甲基氧丁环(AMM O)。三步反应收率分别为76%,96%,85%。用核磁、红外、元素分析和DSC表征了化合物的结构与性能。结构鉴定表明为目标化合物AMM O。
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| 关 键 词： | 有机化学 黏合剂 3-叠氮甲基-3-甲基氧丁环 化学合成 |
| 文章编号： | 1007-7812（2005）03-0057-03 |
| 收稿时间： | 2004-11-18 |
| 修稿时间： | 2004年11月18 |
Synthesis of 3-Azidomethyl-3-Methyloxetane |
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| LI Na,GAN Xiao-xian.Synthesis of 3-Azidomethyl-3-Methyloxetane[J].Chinese Journal of Explosives & Propellants,2005,28(3):57-59. |
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| Authors: | LI Na GAN Xiao-xian |
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| Abstract: | 3-Hydroxymethyl-3-methyl oxetane (HMMO) was prepared by the cyclization of raw materials 1,1,1-tri(hydroxylmethyl) ethane and diethyl carbonate.Under lower temperature,3-methoxytosyl-3-methyl oxetane(MTMO) was synthesized by the reaction of HMMO with 4-toluenesulfonylchloride.3-Azidomethyl-3-methyl oxetane was synthesized by the reaction of MTMO and sodium azide.The yields of the three steps were 76%,96%,85%, respectively .The structure and properties of AMMO were identified by ~1HNMR,FTIR,elemental analysis and DSC .The results show that final product was target compound.AMMO was an important energetic oxetane monomer .It can conduct steady cationic polymerization. |
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| Keywords: | organic chemistry binder 3-azidomethyl-3-methyloxetane chemical synthesis |
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