Hybrid acid–base polymer membranes prepared for application in fuel cells |
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Authors: | Dan Wu Tongwen XuLiang Wu Yonghui Wu |
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Affiliation: | Laboratory of Functional Membranes, School of Chemistry and Materials Science, University of Science and Technology of China (USTC), Hefei, Anhui 230026, People''s Republic of China |
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Abstract: | For application in fuel cells, a series of hybrid acid–base polymer membranes were prepared by blending sulfonated poly(2,6-dimethyl-1,4-phenylene oxide) (SPPO) with (3-aminopropyl)triethoxysilane (A1100) through a sol–gel process. As indicated by scanning electron microscopy, energy-dispersive X-ray analysis, and thermogravimetric analysis, the acid–base interaction improves not only the membrane homogeneity and thermal stability but also the mechanical strength and flexibility. Apart from the low cost, the developed membranes exhibit high proton conductivity and low methanol permeability as compared to Nafion® 117. Further, the optimal membrane shows better performance than Nafion® 117 in a single cell test. All these properties make the hybrid membranes suitable for application in fuel cells. |
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Keywords: | Fuel cell Proton-exchange membrane Hybrid Acid&ndash base SPPO |
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